Triethylsilanol


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C6H15OSi- + Hydrogen cation = Triethylsilanol

By formula: C6H15OSi- + H+ = C6H16OSi

Quantity Value Units Method Reference Comment
Δr1497. ± 9.2kJ/molG+TSGrimm and Bartmess, 1992gas phase
Δr1504. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Δr1471. ± 8.4kJ/molIMREGrimm and Bartmess, 1992gas phase
Δr1477. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimm and Bartmess, 1992
Grimm, D.T.; Bartmess, J.E., The Intrinsic (Gas Phase) Basicity of some Anions Commonly Used in Condensed-Phase Synthesis, J. Am. Chem. Soc., 1992, 114, 4, 1227, https://doi.org/10.1021/ja00030a016 . [all data]

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]


Notes

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