DL-Methionine
- Formula: C5H11NO2S
- Molecular weight: 149.211
- IUPAC Standard InChIKey: FFEARJCKVFRZRR-UHFFFAOYSA-N
- CAS Registry Number: 59-51-8
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- Other names: Racemethionine; DL-2-Amino-4-(methylthio)butanoic acid; DL-CH3SCH2CH2CH(NH2)COOH; α-Amino-γ-methylmercaptobutyric acid; (.+/-.)-Methionine; Acimetion; Banthionine; Cynaron; Dyprin; DL-2-Amino-4-(methylthio)butyric acid; Lobamine; Meonine; Mertionin; Methilanin; Methionine; Methionine, DL-; Metione; Neston; Urimeth; Pedameth; 2-Amino-4-(methylmercapto)butyric acid; Amurex; Methilonin; Methionine dl-form; Metion; Petameth; NSC 9241
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°solid,1 bar | 55.320 | cal/mol*K | N/A | Hutchens, Cole, et al., 1964 |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
69.319 | 298.15 | Hutchens, Cole, et al., 1964 | T = 11 to 348 K. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Enthalpy of phase transition
ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
1.300 | 305.5 | crystaline, II | crystaline, I | Hutchens, Cole, et al., 1964 | Lambda transition over the temperature range 250 to 350 K with a maximum at 305.5 K. |
Entropy of phase transition
ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
4.21 | 305.5 | crystaline, II | crystaline, I | Hutchens, Cole, et al., 1964 | Lambda |
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-1941 |
NIST MS number | 229351 |
UV/Visible spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Saidel and Waldman, 1952 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 11273 |
Instrument | Beckman DU |
Melting point | 281 dec |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hutchens, Cole, et al., 1964
Hutchens, J.O.; Cole, A.G.; Stout, J.W.,
Heat capacities and entropies of L-cystine and L-methionine. The transition of L-methionine near 305.5 K,
J. Biol. Chem., 1964, 239, 591-595. [all data]
Saidel and Waldman, 1952
Saidel, L.J.; Waldman, S.,
J. Biol. Chem., 1952, 197, 285. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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