Ethyl methyl sulphone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-116.25 ± 0.17kcal/molCcrBusfield, Mackle, et al., 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -116.16 ± 0.17 kcal/mol; Heat of combustion corrected for constant pressure
Quantity Value Units Method Reference Comment
Δcliquid-583.12 ± 0.12kcal/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus307.7KN/ABusfield, Ivin, et al., 1961Uncertainty assigned by TRC = 0.5 K; TRC
Tfus307.7KN/ABusfield, Mackle, et al., 1961, 2Uncertainty assigned by TRC = 0.8 K; TRC
Tfus309.KN/APochinok and Limarenko, 1955Uncertainty assigned by TRC = 3. K; TRC
Tfus305.7KN/AMcallan, Cullum, et al., 1951Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Δvap18.6 ± 0.7kcal/molEBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure; ALS

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.70307.7Busfield, Ivin, et al., 1961AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Busfield, Mackle, et al., 1961
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 2 - The standard heats of formation of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1054-1057. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Busfield, Ivin, et al., 1961
Busfield, W.K.; Ivin, K.J.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 3.?Fusion and vaporization heats of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1058, https://doi.org/10.1039/tf9615701058 . [all data]

Busfield, Mackle, et al., 1961, 2
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 2.- The standard heats of formation of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1054. [all data]

Pochinok and Limarenko, 1955
Pochinok, Ya.; Limarenko, A.P., Alkylation of Mercaptans with Alkylaryltriazines, Ukrain. Khim. Zh., 1955, 21, 628-30. [all data]

Mcallan, Cullum, et al., 1951
Mcallan, D.T.; Cullum, T.V.; Dean, R.A.; Fidler, F.A., The Preparation and Properties of Sulfur Compounds Related to Petroleum I. The Dialkyl Sulfides and Disulfides, J. Am. Chem. Soc., 1951, 73, 3627-32. [all data]


Notes

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