Propane, 1,2-dibromo-2-methyl-
- Formula: C4H8Br2
- Molecular weight: 215.914
- IUPAC Standard InChI: InChI=1S/C4H8Br2/c1-4(2,6)3-5/h3H2,1-2H3
- IUPAC Standard InChIKey: SDTXSEXYPROZSZ-UHFFFAOYSA-N
- CAS Registry Number: 594-34-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Isobutylene bromide; 1,2-Dibromo-2-methylpropane; 1,2-Dibromoisobutane
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -150.5 | kJ/mol | Eqk | Rozhnov, Nesterova, et al., 1975 | Gas phase isomerization |
| ΔfH°liquid | -156.6 ± 1.0 | kJ/mol | Cm | Sunner and Wulff, 1974 | Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -157.6 ± 1.1 kJ/mol |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
By formula: C4H8Br2 = C4H8Br2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -8.8 ± 0.3 | kJ/mol | Eqk | Rozhnov, Nesterova, et al., 1975 | liquid phase; Gas phase isomerization |
=
+
By formula: C4H8Br2 = HBr + C4H7Br
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 75.3 | kJ/mol | Cm | Levanova, Rozhnov, et al., 1975 | gas phase; Dehydrohalogenation |
=
+
By formula: C4H8Br2 = C4H8 + Br2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 139.7 ± 0.46 | kJ/mol | Cm | Sunner and Wulff, 1974 | liquid phase |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rozhnov, Nesterova, et al., 1975
Rozhnov, A.M.; Nesterova, T.N.; Mukovnina, G.S.,
Equilibrium in the isomerisation of dibromoalkanes. II. Isomerisation of dibromoisobutanes,
Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 1675-1676. [all data]
Sunner and Wulff, 1974
Sunner, S.; Wulff, C.A.,
The enthalpy of formation of 1,1-dibromo-2-methylpropane,
J. Chem. Thermodyn., 1974, 6, 287-292. [all data]
Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P.,
Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]
Levanova, Rozhnov, et al., 1975
Levanova, S.V.; Rozhnov, A.M.; Plaksina, T.V.; Anisimova, Z.I.,
Dehydrohalogenation of some dihalo derivatives of isobutane,
Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 1440-1441. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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