Methylcyclopropane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil273.85KN/AGragson, Greenlee, et al., 1953Uncertainty assigned by TRC = 0.3 K; TRC
Tboil273.85KN/AGragson, Greenlee, et al., 1953Uncertainty assigned by TRC = 0.3 K; TRC
Tboil273.88KN/AAnonymous, 1952Uncertainty assigned by TRC = 0.2 K; TRC
Tboil277.65KN/ALagerlof, 1918Uncertainty assigned by TRC = 3. K; TRC
Tboil277.65KN/ADemjanoff, 1895Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus96.0 ± 0.3KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple95.640KN/APomerantz, Fookson, et al., 1954Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
5.93263.AStephenson and Malanowski, 1987Based on data from 177. to 278. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
177. to 277.73.78280881.456-44.806Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gragson, Greenlee, et al., 1953
Gragson, J.T.; Greenlee, K.W.; Derfer, J.M.; Boord, C.E., J. Am. Chem. Soc., 1953, 75, 3344-7. [all data]

Anonymous, 1952
Anonymous, R., , Physical Properties of Chemical Substances, Dow Chemical Co., 1952. [all data]

Lagerlof, 1918
Lagerlof, D., Thermodynamic research: reduced formulas for simplified calculations of latent molar heat of evaporation, J. Prakt. Chem., 1918, 98, 136. [all data]

Demjanoff, 1895
Demjanoff, N., Methyltrimethylene, Ber. Dtsch. Chem. Ges., 1895, 28, 21. [all data]

Pomerantz, Fookson, et al., 1954
Pomerantz, P.; Fookson, A.; Mears, T.W.; Rothberg, S.; Howard, F.L., Synth. and Phys. Prop. of Several Aliphatic and Alicyclic Hydrocarbons hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1954, 52, 59-65. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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