Carbonic dibromide
- Formula: CBr2O
- Molecular weight: 187.818
- IUPAC Standard InChI: InChI=1S/CBr2O/c2-1(3)4
- IUPAC Standard InChIKey: MOIPGXQKZSZOQX-UHFFFAOYSA-N
- CAS Registry Number: 593-95-3
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -145. ± 0.8 | kJ/mol | Cm | Anthoney, Finch, et al., 1970 | Heat of hydrolysis |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 31.0 ± 1.3 | kJ/mol | V | Anthoney, Finch, et al., 1970 | Heat of hydrolysis |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
+
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 33.9 ± 0.42 | kJ/mol | Eqk | Dunning and Pritchard, 1972 | gas phase |
| ΔrH° | 4.3 ± 0.4 | kJ/mol | Eqk | Schumacher and Bergmann, 1931 | gas phase |
+
= 2
+
By formula: CBr2O + H2O = 2HBr + CO2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -205.3 ± 0.67 | kJ/mol | Cm | Anthoney, Finch, et al., 1970 | liquid phase; Heat of hydrolysis |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Anthoney, Finch, et al., 1970
Anthoney, M.E.; Finch, A.; Gardner, P.J.,
The enthalpy of hydrolysis and thermodynamic properties of carbonyl bromide,
J. Chem. Thermodyn., 1970, 2, 697-700. [all data]
Dunning and Pritchard, 1972
Dunning, B.K.; Pritchard, H.O.,
The enthalpy of formation of bromophosgene,
J. Chem. Thermodyn., 1972, 4, 213-218. [all data]
Schumacher and Bergmann, 1931
Schumacher, H.-J.; Bergmann, P.,
Die kinetik und photochemie des bromphosgens,
Z. Phys. Chem., 1931, 13, 269-284. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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