Bismuthine, trimethyl-
- Formula: C3H9Bi
- Molecular weight: 254.0840
- IUPAC Standard InChIKey: AYDYYQHYLJDCDQ-UHFFFAOYSA-N
- CAS Registry Number: 593-91-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Trimethylbismuth; Trimethylbismuthine; Bismuth trimethyl; Trimethylbismutin
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 194. ± 14. | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 158. ± 14. | kJ/mol | Review | Martinho Simões | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -2912. ± 14. | kJ/mol | CC-SB | Long and Sackman, 1954 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 36.0 ± 1.3 | kJ/mol | CC-SB | Amberger, 1961 | MS |
ΔvapH° | 35.8 | kJ/mol | N/A | Amberger, 1961, 2 | Based on data from 215. to 380. K.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(g) = C2H6Bi (g) +
(g)
By formula: C3H9Bi (g) = C2H6Bi (g) + CH4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 209. to 222. | kJ/mol | N/A | Smith and Patrick, 1983 | |
ΔrH° | 218. ± 17. | kJ/mol | N/A | McMillen and Golden, 1982 |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 12398 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Long and Sackman, 1954
Long, L.H.; Sackman, J.F.,
The heat of formation of bismuth trimethyl,
Trans. Faraday Soc., 1954, 50, 1177, https://doi.org/10.1039/tf9545001177
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Amberger, 1961
Amberger, E.,
Chem. Ber., 1961, 94, 1447. [all data]
Amberger, 1961, 2
Amberger, Eberhard,
Hydride des Wismuts,
Chem. Ber., 1961, 94, 6, 1447-1452, https://doi.org/10.1002/cber.19610940607
. [all data]
Smith and Patrick, 1983
Smith, G.P.; Patrick, R.,
Int. J. Chem. Kinet., 1983, 15, 167. [all data]
McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M.,
Hydrocarbon bond dissociation energies,
Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]
Notes
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- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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