e-Diazene, bis(bicyclo[2.2.1]hept-1-yl)-
- Formula: C14H22N2
- Molecular weight: 218.3379
- CAS Registry Number: 59388-65-7
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
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Individual Reactions
C14H22N2 = C14H22N2
By formula: C14H22N2 = C14H22N2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -67.9 ± 3.8 | kJ/mol | Kin | Schmittel and Ruchardt, 1987 | solid phase; solvent: Mesitylene |
| ΔrH° | -81. ± 2. | kJ/mol | Eqk | Schmittel, Schultz, et al., 1981 | liquid phase; solvent: Dimethyl formamide |
| ΔrH° | -79. ± 2. | kJ/mol | Eqk | Schmittel, Schultz, et al., 1981 | liquid phase; solvent: Dodecane |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schmittel and Ruchardt, 1987
Schmittel, M.; Ruchardt, C.,
Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes,
J. Am. Chem. Soc., 1987, 109, 2750-2759. [all data]
Schmittel, Schultz, et al., 1981
Schmittel, M.; Schultz, A.; Ruchardt, C.; Hadicke, E.,
Aliphatic azo compounds. XIII. cis- and trans-1-Azonorbornane,
Chem. Ber., 1981, 114, 3533-3548. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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