Mercury, dimethyl-
- Formula: C2H6Hg
- Molecular weight: 230.66
- IUPAC Standard InChI: InChI=1S/2CH3.Hg/h2*1H3;
- IUPAC Standard InChIKey: ATZBPOVXVPIOMR-UHFFFAOYSA-N
- CAS Registry Number: 593-74-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Dimethylmercury; (CH3)2Hg
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | 14.8 ± 0.93 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | 12.4 ± 0.50 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | 13.8 ± 0.72 | kcal/mol | Review | Martinho Simões | Selected data. Average of the values from Carson, Carson, et al., 1952 and Hartley, Pritchard, et al., 1950. |
| ΔfH°liquid | 14.3 ± 0.1 | kcal/mol | CC-SB | Carson, Carson, et al., 1952 | Value corrected based on a set of ancillary data by J.A. Martinho Simões; Please also see Cox and Pilcher, 1970. The enthalpy of combustion is not reported in Carson, Carson, et al., 1952. |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | 38.77 | kcal/mol | Review | Martinho Simões | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -431.81 | kcal/mol | CC-SB | Berthelot, 1899 | Please also see Berthelot, 1900. |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Carson, Carson, et al., 1952
Carson, A.S.; Carson, E.M.; Wilmshurst, B.,
Nature, 1952, 170, 320. [all data]
Hartley, Pritchard, et al., 1950
Hartley, K.; Pritchard, H.O.; Skinner, H.A.,
Thermochemistry of metallic alkyls. III.?mercury dimethyl and mercury methyl halides,
Trans. Faraday Soc., 1950, 46, 1019, https://doi.org/10.1039/tf9504601019
. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Berthelot, 1899
Berthelot, M.,
Compt. Rend., 1899, 129, 918. [all data]
Berthelot, 1900
Berthelot, M.,
Ann. Chim. Phys., 1900, 20, 158. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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