Vinyl bromide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas79.2 ± 1.9kJ/molChydLacher, Kianpour, et al., 1957Reanalyzed by Cox and Pilcher, 1970, Original value = 78.2 ± 1.9 kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
107.5288.Mehl, 1934 
107.9288.Mehl, 1934, 2One measurement.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil289.KN/APCR Inc., 1990BS
Tboil289.0KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus133.61KN/ADreisbach, 1955Uncertainty assigned by TRC = 0.02 K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
289.21.00Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
27.3239.AStephenson and Malanowski, 1987Based on data from 224. to 319. K. See also Dykyj, 1970.; AC
24.8274.N/AGuyer, Sch«65533»tze, et al., 1937Based on data from 186. to 289. K. See also Boublik, Fried, et al., 1984.; AC
26.9270.N/AMehl, 1934, 3Based on data from 207. to 285. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
185.7 to 289.4.368691219.308-9.129Guyer, Sch«65533»tze, et al., 1937Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Bromo-1-chloroethane = Vinyl bromide + Hydrogen chloride

By formula: C2H4BrCl = C2H3Br + HCl

Quantity Value Units Method Reference Comment
Δr66. ± 2.kJ/molEqkBusheva, Levanova, et al., 1980gas phase; Dehydrohalogenation

2Hydrogen + Vinyl bromide = Hydrogen bromide + Ethane

By formula: 2H2 + C2H3Br = HBr + C2H6

Quantity Value Units Method Reference Comment
Δr-199.2 ± 1.9kJ/molChydLacher, Kianpour, et al., 1957gas phase

Ethane, 1,1-dibromo- = Hydrogen bromide + Vinyl bromide

By formula: C2H4Br2 = HBr + C2H3Br

Quantity Value Units Method Reference Comment
Δr70. ± 3.kJ/molEqkLevanova, Rozhnov, et al., 1970gas phase

Ethane, 1,2-dibromo- = Hydrogen bromide + Vinyl bromide

By formula: C2H4Br2 = HBr + C2H3Br

Quantity Value Units Method Reference Comment
Δr80. ± 2.kJ/molEqkLevanova, Rozhnov, et al., 1970gas phase

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.450.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lacher, Kianpour, et al., 1957
Lacher, J.R.; Kianpour, A.; Montgomery, P.; Knedler, H.; Park, J.D., Reaction heats of organic halogen compounds. IX. The catalytic hydrogenation of vinyl and perfluorovinyl bromide, J. Phys. Chem., 1957, 61, 1125-1126. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Mehl, 1934
Mehl, W., Die spezifische Wärme einiger flüssiger Kältemittel, Z. ges. Kalte-Ind., 1934, 41, 152-153. [all data]

Mehl, 1934, 2
Mehl, W., Physikalishce Eigenschaften des Vinylbromids, Z. Phys. Chem., 1934, A169, 312-313. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Dreisbach, 1955
Dreisbach, R.R., Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Guyer, Sch«65533»tze, et al., 1937
Guyer, A.; Sch«65533»tze, H.; Weidenmann, M., «65533»ber einige thermische Eigenschaften des Vinylbromids, Helv. Chim. Acta, 1937, 20, 1, 936-949, https://doi.org/10.1002/hlca.193702001136 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Mehl, 1934, 3
Mehl, W., Z. Phys. Chem. Abt. A, 1934, 164, 312. [all data]

Busheva, Levanova, et al., 1980
Busheva, L.I.; Levanova, S.V.; Rodova, R.M.; Rozhnov, A.M., Thermocatalytic reactions of 1,1-bromochloroethane, Russ. J. Phys. Chem. (Engl. Transl.), 1980, 54, 1403-1404. [all data]

Levanova, Rozhnov, et al., 1970
Levanova, S.V.; Rozhnov, A.M.; Sedov, S.M.; Starkov, V.Ya.; Manzohos, V.N., Equilibrium reactions of dibromoethane, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1970, 13, 62-65. [all data]

Waggott and Davies, 1984
Waggott, A.; Davies, I.W., Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas Chromatography, References