(E)-1,2-Diiodoethylene
- Formula: C2H2I2
- Molecular weight: 279.8462
- CAS Registry Number: 590-27-2
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Gas phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 207.4 ± 0.84 | kJ/mol | Eqk | Furuyama, Golden, et al., 1968 | Reanalyzed by Cox and Pilcher, 1970, Original value = 206. ± 0.4 kJ/mol |
Phase change data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 346.2 | K | N/A | Furuyama, Golden, et al., 1969 | Uncertainty assigned by TRC = 1. K; TRC |
Tfus | 344.9 | K | N/A | Andrews and Keefer, 1951 | Uncertainty assigned by TRC = 1. K; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
42.3 | 365. | A | Stephenson and Malanowski, 1987 | Based on data from 350. to 403. K. See also Dykyj, 1970.; AC |
43.8 | 365. | N/A | Noyes, Noyes, et al., 1950 | Based on data from 350. to 403. K.; AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
40.7 | 258. | ME | Broadway and Fraser, 1933 | Based on data from 253. to 265. K. See also Jones, 1960 and Stephenson and Malanowski, 1987.; AC |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C2H2I2 = C2H2 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 83.3 | kJ/mol | Eqk | Furuyama, Golden, et al., 1968 | gas phase |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Furuyama, Golden, et al., 1968
Furuyama, S.; Golden, D.M.; Benson, S.W.,
The thermochemistry of the gas-phase equilibria trans-1,2-diiodoethylene = acetylene + I2 and trans-1,2-diiodoethylene = cis-1,2-diiodoethylene,
J. Phys. Chem., 1968, 72, 3204-3208. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Furuyama, Golden, et al., 1969
Furuyama, S.; Golden, D.M.; Benson, S.W.,
The Thermochemistry of the Gas Phase Equilibria i-C3H7I = C3H6 + HI, n-C3H7I = i-C3H7I and C3H6 + 2HI = C3H8 + I2,
J. Chem. Thermodyn., 1969, 1, 363-75. [all data]
Andrews and Keefer, 1951
Andrews, L.J.; Keefer, R.M.,
The Argentation of Organic Iodides,
J. Am. Chem. Soc., 1951, 73, 5733-5736. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Noyes, Noyes, et al., 1950
Noyes, Richard M.; Noyes, Winninette A.; Steinmetz, Hyman,
Vapor Pressures of cis and trans Disubstituted Ethylenes,
J. Am. Chem. Soc., 1950, 72, 1, 33-34, https://doi.org/10.1021/ja01157a008
. [all data]
Broadway and Fraser, 1933
Broadway, L.F.; Fraser, Ronald G.J.,
111. The vapour pressure of trans-di-iodoethylene,
J. Chem. Soc., 1933, 429, https://doi.org/10.1039/jr9330000429
. [all data]
Jones, 1960
Jones, A.H.,
Sublimation Pressure Data for Organic Compounds.,
J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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