(E)-1-Bromo-1-propene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas43.9 ± 4.2kJ/molEqkAlfassi, Golden, et al., 1973Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 48.1 kJ/mol

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

(Z)-1-Bromo-1-propene = (E)-1-Bromo-1-propene

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr3.1 ± 0.1kJ/molCisoAbell and Adolf, 1969gas phase; HBr catalyst

(E)-1-Bromo-1-propene = 1-Propene, 3-bromo-

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr1.3 ± 0.50kJ/molEqkAlfassi, Golden, et al., 1973gas phase

(E)-1-Bromo-1-propene = (Z)-1-Bromo-1-propene

By formula: C3H5Br = C3H5Br

Quantity Value Units Method Reference Comment
Δr-1.84 ± 0.10kJ/molEqkSharonov and Rozhnov, 1971gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Alfassi, Golden, et al., 1973
Alfassi, Z.B.; Golden, D.M.; Benson, S.W., The thermochemistry of the isomerization of 3-halopropenes (allyl halides) to 1-halopropenes; entropy and enthalpy of formation contribution of the Cd-(H)(X) group, J. Chem. Thermodyn., 1973, 5, 411-420. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Abell and Adolf, 1969
Abell, P.I.; Adolf, P.K., HBr catalyzed photoisomerization of allyl halides, J. Chem. Thermodyn., 1969, 1, 333-338. [all data]

Sharonov and Rozhnov, 1971
Sharonov, K.G.; Rozhnov, A.M., Isomerization of 1-bromo-1-propenes, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1971, 14, 577-560. [all data]


Notes

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