H2CCl+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

(CH2Cl+ • Chloromethane) + Chloromethane = (CH2Cl+ • 2Chloromethane)

By formula: (CH2Cl+ • CH3Cl) + CH3Cl = (CH2Cl+ • 2CH3Cl)

Quantity Value Units Method Reference Comment
Δr5.7kcal/molHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable
Quantity Value Units Method Reference Comment
Δr6.9cal/mol*KHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.4182.HPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

CH2Cl+ + Chloromethane = (CH2Cl+ • Chloromethane)

By formula: CH2Cl+ + CH3Cl = (CH2Cl+ • CH3Cl)

Quantity Value Units Method Reference Comment
Δr6.9kcal/molHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable
Quantity Value Units Method Reference Comment
Δr-3.7cal/mol*KHPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
8.1312.HPMSLuczynski, Malicki, et al., 1974gas phase; DG from graph, Entropy change is questionable

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Luczynski, Malicki, et al., 1974
Luczynski, Z.; Malicki, W.; Wincel, H., Positive Ion Reactions of Methyl Cloride in the Gas Phase, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 3, 321, https://doi.org/10.1016/0020-7381(74)85009-6 . [all data]


Notes

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