Heptane, 3-methyl-
- Formula: C8H18
- Molecular weight: 114.2285
- IUPAC Standard InChIKey: LAIUFBWHERIJIH-UHFFFAOYSA-N
- CAS Registry Number: 589-81-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Stereoisomers:
- Other names: 3-Methylheptane; 2-Ethylhexane
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Normal boiling point
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Tboil (K) | Reference | Comment |
---|---|---|
392.1 | Majer and Svoboda, 1985 | |
391.7 | Slesareva and Lyubomilov, 1973 | Uncertainty assigned by TRC = 1. K; TRC |
392. | Slesareva and Lyubomilov, 1973 | Uncertainty assigned by TRC = 2. K; TRC |
390. | Freidlin, Nazarova, et al., 1961 | Uncertainty assigned by TRC = 2. K; TRC |
392.08 | Desty and Whyman, 1957 | Uncertainty assigned by TRC = 0.2 K; TRC |
391.95 | Anonymous, 1955 | Uncertainty assigned by TRC = 0.3 K; TRC |
390.85 | Neff and Hickman, 1955 | Uncertainty assigned by TRC = 0.3 K; not certain that this was measured; TRC |
388.15 | Wichterle and Vogel, 1954 | Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average |
391.95 | Roebuck and Evering, 1953 | Uncertainty assigned by TRC = 0.4 K; TRC |
392.1 | Anonymous, 1951 | Uncertainty assigned by TRC = 0.3 K; TRC |
392.11 | Anonymous, 1951 | Uncertainty assigned by TRC = 0.2 K; TRC |
392.04 | Boord, Henne, et al., 1949 | Uncertainty assigned by TRC = 0.3 K; TRC |
391.75 | Buck, Elsner, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
392.04 | Fenske, Braun, et al., 1947 | Uncertainty assigned by TRC = 0.15 K; TRC |
392.04 | Boord, Greenlee, et al., 1946 | Uncertainty assigned by TRC = 0.3 K; TRC |
392.07 | Forziati, Glasgow, et al., 1946 | Uncertainty assigned by TRC = 0.01 K; TRC |
392.07 | Anonymous, 1942 | Uncertainty assigned by TRC = 0.1 K; TRC |
392.25 | Henne, Chanan, et al., 1941 | Uncertainty assigned by TRC = 0.5 K; TRC |
392.25 | Anonymous, 1940 | Uncertainty assigned by TRC = 0.2 K; TRC |
392.25 | Manzoni-Ansidei, 1940 | Uncertainty assigned by TRC = 0.6 K; TRC |
392.25 | Anonymous, 1939 | Uncertainty assigned by TRC = 0.3 K; TRC |
392.2 | Wibaut, Hoog, et al., 1939 | Uncertainty assigned by TRC = 0.3 K; TRC |
390.95 | Gibson, 1938 | Uncertainty assigned by TRC = 1. K; TRC |
392.25 | Smittenberg, Hoog, et al., 1938 | Uncertainty assigned by TRC = 0.2 K; TRC |
390.75 | Leslie and White, 1935 | Uncertainty assigned by TRC = 0.6 K; TRC |
391.75 | Dietrich, 1933 | Uncertainty assigned by TRC = 1. K; TRC |
391.15 | Timmermans, 1921 | Uncertainty assigned by TRC = 2. K; TRC |
390.75 | Clarke, 1909 | Uncertainty assigned by TRC = 0.5 K; TRC |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Slesareva and Lyubomilov, 1973
Slesareva, L.A.; Lyubomilov, V.I.,
The Condensation of Glycols by the Markovnikov-Guerbet Reaction,
Zh. Org. Khim., 1973, 9, 2025-8. [all data]
Freidlin, Nazarova, et al., 1961
Freidlin, L.K.; Nazarova, N.M.; Palii, A.I.,
Alkylation of Normal Paraffins with Olefins at High Temperatures and Pressures,
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1961, 1961, No. 4, 714-21. [all data]
Desty and Whyman, 1957
Desty, D.H.; Whyman, B.H.F.,
Anal. Chem., 1957, 29, 320. [all data]
Anonymous, 1955
Anonymous, R.,
, Am. Pet. Inst. Res. Proj. 45, Tech. Rep. 14, No. 1, Ohio State Univ., 1955. [all data]
Neff and Hickman, 1955
Neff, J.A.; Hickman, J.B.,
Total Pressure of Certain Binary Liquid Mixtures,
J. Phys. Chem., 1955, 59, 42-5. [all data]
Wichterle and Vogel, 1954
Wichterle, O.; Vogel, J.,
Chem. Listy, 1954, 48, 1225. [all data]
Roebuck and Evering, 1953
Roebuck, A.K.; Evering, B.L.,
Sulfuric Acid Isomerization of Methylalkanes, Dimethylalkanes, and Dimethylcyclohexanes,
J. Am. Chem. Soc., 1953, 75, 1631. [all data]
Anonymous, 1951
Anonymous, R.,
, Sunbury Rep. No. 4199, Anglo-Iranian Oil Co., 1951. [all data]
Boord, Henne, et al., 1949
Boord, C.E.; Henne, A.L.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M.,
The Grignard Reagent in hydrocarbon synthesis,
Ind. Eng. Chem., 1949, 41, 609. [all data]
Buck, Elsner, et al., 1949
Buck, F.R.; Elsner, B.B.; Henshall, T.; Moore, T.S.; Murray, A.R.; Morrell, S.H.; Muller, G.; Plant, M.M.T.; Smith, J.C.; Wallsgrove, E.R.,
Hydrocarbon synthesis.,
J. Inst. Pet., 1949, 35, 631. [all data]
Fenske, Braun, et al., 1947
Fenske, M.R.; Braun, W.G.; Wiegand, R.V.; Quiggle, D.; McCormick, R.H.; Rank, D.H.,
Raman Spectra of Hydrocarbons,
Anal. Chem., 1947, 19, 700. [all data]
Boord, Greenlee, et al., 1946
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L.,
The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Weight, Am. Pet. Inst. Res. Proj. 45, Eighth Annu. Rep., Ohio State Univ., June 30, 1946. [all data]
Forziati, Glasgow, et al., 1946
Forziati, A.F.; Glasgow, A.R.; Willingham, C.B.; Rossini, F.D.,
Specification adn Properties of 29 Paraffin, 4 Alkylcyclopentanes, 10 Alkylcyclohexanes and 8 Alkylbenzene Hydrocarbons,
J. Res. Natl. Bur. Stand. (U. S.), 1946, 36, 129. [all data]
Anonymous, 1942
Anonymous, R.,
, Am. Pet. Inst. Res. Proj. 6, Natl. Bur. Stand., 1942. [all data]
Henne, Chanan, et al., 1941
Henne, A.L.; Chanan, H.H.; Turk, A.,
Olefins and Diolefins from Allylic Chlorides,
J. Am. Chem. Soc., 1941, 63, 3474-6. [all data]
Anonymous, 1940
Anonymous, R.,
, Am. Pet. Inst. Hydrocarbon Res. Proj., Second Annu. Rep., Ohio State Univ., Aug. 31, 1940. [all data]
Manzoni-Ansidei, 1940
Manzoni-Ansidei, R.,
Parachors of Branched Chain Paraffin Hydrocarbons,
Boll. Sci. Fac. Chim. Ind. Bologna, 1940, 1940, 201. [all data]
Anonymous, 1939
Anonymous, R.,
, Am. Pet. Inst. Hydrocarbon Res. Proj., First Annu. Rep., Ohio State Univ., Aug. 31, 1939. [all data]
Wibaut, Hoog, et al., 1939
Wibaut, J.P.; Hoog, H.; Langedijk, S.L.; Overhoff, J.; Smittenberg, J.; Benninga, N.; Bouman, G.P.; van Dijk, H.; Gaade, W.; Geldof, H.; Hackmann, J.Th.; Jonker, E.W.; Paap, T.; Zuiderweg, F.J.,
Study on the Preparation and the Physical Constants of A Number of Alkanes and Cycloalkanes,
Recl. Trav. Chim. Pays-Bas, 1939, 58, 329. [all data]
Gibson, 1938
Gibson, J.D.,
Olefins of Types I and II from Butadiene and the Relation of Their Physical Constants to Structure, Ph.D. Thesis, Ohio State Univ., Columbus, OH, 1938. [all data]
Smittenberg, Hoog, et al., 1938
Smittenberg, J.; Hoog, H.; Henkes, R.A.,
Freezing Points of A Number of Pure Hydrocarbons of the Gasoline Boiling Range and of Some of their Binary Mixtures,
J. Am. Chem. Soc., 1938, 60, 17. [all data]
Leslie and White, 1935
Leslie, R.T.; White, J.D.,
Present Status or the Isolation and Identification of The Volatile Hydrocarbons in a Midcontinent Petroleum,
J. Res. Natl. Bur. Stand. (U. S.), 1935, 15, 211. [all data]
Dietrich, 1933
Dietrich, M.A.,
Syntheses in the olefin series octenes of type I and type II, Ph.D. Thesis, Ohio State Univ., Columbus, OH, 1933. [all data]
Timmermans, 1921
Timmermans, J.,
The Freezing Points of Organic Substances IV. New Exp. Determinations,
Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]
Clarke, 1909
Clarke, L.,
J. Am. Chem. Soc., 1909, 31, 558. [all data]
Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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