4-Octanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
337.6298.5Cline and Andrews, 1931T = 102 to 311 K. Value is unsmoothed experimental datum.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tc625.1 ± 0.5KN/AGude and Teja, 1995 
Tc625.1KN/ATeja, Lee, et al., 1989TRC
Tc625.1KN/AAnselme and Teja, 1988Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Vc0.515l/molN/AGude and Teja, 1995 
Quantity Value Units Method Reference Comment
ρc1.94mol/lN/AGude and Teja, 1995 
ρc1.94mol/lN/AAnselme and Teja, 1988Uncertainty assigned by TRC = 0.05 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap67.2 ± 0.5kJ/molGSVerevkin and Schick, 2007Based on data from 288. to 322. K.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
57.3358.AStephenson and Malanowski, 1987Based on data from 343. to 450. K.; AC
54.8379.N/ASachek, Markovnik, et al., 1984Based on data from 364. to 449. K.; AC
62.1356.N/AWilhoit and Zwolinski, 1973Based on data from 341. to 449. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
283. to 353.5.085221816.393-83.125Geiseler, Fruwert, et al., 1966Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cline and Andrews, 1931
Cline, J.K.; Andrews, D.H., Thermal energy studies. III. The octanols, J. Am. Chem. Soc., 1931, 53, 3668-3673. [all data]

Gude and Teja, 1995
Gude, M.; Teja, A.S., Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols, J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Anselme and Teja, 1988
Anselme, M.J.; Teja, A.S., Critical Temperatures and Densities of Isomeric Alkanols with Six to Ten Carbon Atoms, Fluid Phase Equilib., 1988, 40, 127-34. [all data]

Verevkin and Schick, 2007
Verevkin, Sergey P.; Schick, Christoph, Vapour pressures and heat capacity measurements on the C7--C9 secondary aliphatic alcohols, The Journal of Chemical Thermodynamics, 2007, 39, 5, 758-766, https://doi.org/10.1016/j.jct.2006.10.007 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Sachek, Markovnik, et al., 1984
Sachek, A.I.; Markovnik, V.S.; Peshchenko, A.D.; Shvaro, A.V.; Andreevskii, D.N., Khim. Prom-st. (Moscow), 1984, 337. [all data]

Wilhoit and Zwolinski, 1973
Wilhoit, R.C.; Zwolinski, B.J., Physical and thermodynamic properties of aliphatic alcohols, J. Phys. Chem. Ref. Data Suppl., 1973, 1, 2, 1. [all data]

Geiseler, Fruwert, et al., 1966
Geiseler, Gerhard; Fruwert, Johanna; Hüttig, Rainer, Dampfdruck- und Schwingungsverhalten der stellungsisomeren n-Octanole und hydroxydeuterierten n-Octanole, Chem. Ber., 1966, 99, 5, 1594-1601, https://doi.org/10.1002/cber.19660990525 . [all data]


Notes

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