Difluoro-bis(2-fluoro-2,2-dinitroethoxy)methane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-1297.9 ± 6.7kJ/molCcbAvdonin, Kirpichev, et al., 1991 
Quantity Value Units Method Reference Comment
Δcliquid-1982.9 ± 6.7kJ/molCcbAvdonin, Kirpichev, et al., 1991 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
72.7340.Minier and Behrens, 1997Based on data from 323. to 357. K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Avdonin, Kirpichev, et al., 1991
Avdonin, V.V.; Kirpichev, E.P.; Rubtsov, Yu.I.; Fadeev, M.A.; Oreshko, G.V.; Eremenko, L.T., Synthesis and thermochemical properties of some fluorine-containing formals, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 2189-2193. [all data]

Minier and Behrens, 1997
Minier, Leanna M.G.; Behrens, Richard, Thermal decomposition mechanisms of bis(2-fluoro-2,2-dinitroethyl) formal (FEFO) and bis(2-fluoro-2,2-dinitroethyl) difluoroformal (DFF) from simultaneous thermogravimetric modulated beam mass spectrometry (STMBMS) measurements, Propellants Explos. Pyrotech., 1997, 22, 1, 23-33, https://doi.org/10.1002/prep.19970220107 . [all data]


Notes

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