3-Quinolinamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas49.81 ± 0.53kcal/molCcbRibeiro da Silva, Matos, et al., 1993 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid25.17 ± 0.48kcal/molCcbRibeiro da Silva, Matos, et al., 1993 
Quantity Value Units Method Reference Comment
Δcsolid-1144.9 ± 0.38kcal/molCcbRibeiro da Silva, Matos, et al., 1993 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus429.65KN/ACumper, Ginman, et al., 1963Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub24.6 ± 0.2kcal/molCRibeiro da Silva, Matos, et al., 1993ALS
Δsub24.64kcal/molN/ARibeiro da Silva, Matos, et al., 1993DRB
Δsub24.6 ± 0.2kcal/molMEda Silva, Matos, et al., 1993Based on data from 329. to 345. K.; AC
Δsub25.0 ± 1.1kcal/molCda Silva, Matos, et al., 1993AC

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
24.2 ± 0.2337.MEda Silva, Matos, et al., 1993Based on data from 329. to 345. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C9H7N2- + Hydrogen cation = 3-Quinolinamine

By formula: C9H7N2- + H+ = C9H8N2

Quantity Value Units Method Reference Comment
Δr353.9 ± 2.9kcal/molG+TSBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline
Quantity Value Units Method Reference Comment
Δr346.7 ± 2.7kcal/molIMRBBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C9H7N2- + Hydrogen cation = 3-Quinolinamine

By formula: C9H7N2- + H+ = C9H8N2

Quantity Value Units Method Reference Comment
Δr353.9 ± 2.9kcal/molG+TSBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline
Quantity Value Units Method Reference Comment
Δr346.7 ± 2.7kcal/molIMRBBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Matos, et al., 1993
Ribeiro da Silva, M.A.V.; Matos, M.A.R.; Monte, M.J.S.; Alves, M.C.B.; Vieira, J.M.A.P., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 3-,5-,6-, and 8-aminoquinoline, J. Chem. Thermodyn., 1993, 25, 579-590. [all data]

Cumper, Ginman, et al., 1963
Cumper, C.W.N.; Ginman, R.F.A.; Redford, D.G.; Vogel, A.I., Physical Properties and Chemical Constitution. Part XXXVIII. The Electric Dipole Moments of Aminopyridines and Aminoquinolines., J. Chem. Soc., 1963, 1963, 1731. [all data]

da Silva, Matos, et al., 1993
da Silva, Manuel A.V. Ribeiro; Matos, M. Agostinha R.; Monte, Manuel J.S.; Alves, M. Céu B.; Vieira, João M.A.P., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 3-, 5-, 6-, and 8-aminoquinoline, The Journal of Chemical Thermodynamics, 1993, 25, 5, 579-590, https://doi.org/10.1006/jcht.1993.1052 . [all data]

Breuker, Knochenmuss, et al., 1999
Breuker, K.; Knochenmuss, R.; Zenobi, R., Gas-phase basicities of deprotonated matrix-assisted laser desorption/ionization matrix molecules, Int. J. Mass Spectrom., 1999, 184, 1, 25-38, https://doi.org/10.1016/S1387-3806(98)14200-8 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References