Propylene Glycol
- Formula: C3H8O2
- Molecular weight: 76.0944
- IUPAC Standard InChIKey: DNIAPMSPPWPWGF-UHFFFAOYSA-N
- CAS Registry Number: 57-55-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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- Stereoisomers:
- Other names: 1,2-Propanediol; α-Propylene glycol; Methylethyl glycol; Methylethylene glycol; Monopropylene glycol; PG 12; Sirlene; 1,2-Dihydroxypropane; 1,2-Propylene glycol; 2-Hydroxypropanol; 2,3-Propanediol; Propane-1,2-diol; Dowfrost; Propylene glycol USP; 1,2-Propylenglykol; Solar winter ban; Sentry Propylene Glycol; Isopropylene glycol; Ucar 35; Solargard P; Ilexan P; Prolugen; Trimethyl glycol; 1,2-Propandiol; Propylenglycol; (RS)-1,2-Propanediol; (.+/-.)-1,2-Propanediol; DL-1,2-Propanediol; NSC 69860; DL-Propylene glycol; propylene glycol (1,2-propanediol); 1,2-propanediol (propylene glycol); propanediol; Methyl glycol
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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
ΔvapH° (kcal/mol) | Method | Reference | Comment |
---|---|---|---|
16.1 ± 0.1 | GS | Verevkin, Emel'yanenko, et al., 2009 | Based on data from 284. to 331. K.; AC |
18. | EB | Chylinski, Fras, et al., 2004 | Based on data from 293. to 423. K.; AC |
15.4 ± 0.05 | GS | Verevkin, 2004 | Author later recalculated this earlier value in a later paper Verevkin, Emel'yanenko, et al., 2009. The recalculated value was reported to be 68.5±0.5; AC |
14.9 | TGA | Tatavarti, Dollimore, et al., 2002 | Based on data from 366. to 396. K.; AC |
15.2 ± 0.07 | EB | Wilding, Wilson, et al., 1991 | Based on data from 348. to 453. K. See also Verevkin, 2004.; AC |
17.0 ± 0.02 | C | Knauth and Sabbah, 1990 | ALS |
17.0 | N/A | Knauth and Sabbah, 1990 | DRB |
15.5 | N/A | Gardner and Hussain, 1972 | DRB |
15.5 | EB | Thomas and Meatyard, 1966 | Based on data from 359. to 461. K. See also Verevkin, 2004.; AC |
References
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, Emel'yanenko, et al., 2009
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Nell, Gernot,
1,2-Propanediol. Comprehensive experimental and theoretical study,
The Journal of Chemical Thermodynamics, 2009, 41, 10, 1125-1131, https://doi.org/10.1016/j.jct.2009.04.019
. [all data]
Chylinski, Fras, et al., 2004
Chylinski, Krzysztof; Fras, Zbigniew; Malanowski, Stanislaw K.,
Vapor-Liquid Equilibrium for Propylene Glycol + 2-(2-Hexyloxyethoxy)ethanol and 1-Methyl-2-pyrrolidone + 1-Methoxypropan-2-ol «8224»,
J. Chem. Eng. Data, 2004, 49, 1, 18-23, https://doi.org/10.1021/je034096z
. [all data]
Verevkin, 2004
Verevkin, Sergey P.,
Determination of vapor pressures and enthalpies of vaporization of 1,2-alkanediols,
Fluid Phase Equilibria, 2004, 224, 1, 23-29, https://doi.org/10.1016/j.fluid.2004.05.010
. [all data]
Tatavarti, Dollimore, et al., 2002
Tatavarti, Aditya S.; Dollimore, David; Alexander, Kenneth S.,
A thermogravimetric analysis of non-polymeric pharmaceutical plasticizers: Kinetic analysis, method validation, and thermal stability evaluation,
AAPS PharmSci, 2002, 4, 4, 231-242, https://doi.org/10.1208/ps040445
. [all data]
Wilding, Wilson, et al., 1991
Wilding, W.V.; Wilson, L.C.; Wilson, G.M.,
Vapor-liquid equilibrium measurements on eight binary mixtures: DIPPR Projects 805(A)/89 and 805(E)/89,
AIChE Data Ser., 1991, 1, 6. [all data]
Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R.,
Energetics of inter- and intramolecular bonds in alkanediols. IV. The thermochemical study of 1,2-alkanediols at 298.15 K,
Thermochim. Acta, 1990, 164, 145-152. [all data]
Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S.,
The standard enthalpies of formation of some aliphatic diols,
J. Chem. Thermodyn., 1972, 4, 819-827. [all data]
Thomas and Meatyard, 1966
Thomas, Leo H.; Meatyard, R.,
Viscosity and molecular association. Part VI. Association of dihydric alcohols and phenols,
J. Chem. Soc., A, 1966, 92, https://doi.org/10.1039/j19660000092
. [all data]
Notes
Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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