Phenanthrene, tetradecahydro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
330.1313.Gudinowicz, Campbell, et al., 1963T = 313 to 583 K.

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
289.5298.Nuzzi, 1982T = 193 to 403 K.
345.6298.Nuzzi, 1982T = 193 to 403 K.
281.2298.Nuzzi, 1982T = 193 to 403 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
55.7470.EBRohác, Censký, et al., 2000Based on data from 455. to 551. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
11.155313.Nuzzi, 1982DH
10.481273.Nuzzi, 1982DH
11.832283.Nuzzi, 1982DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
35.64313.Nuzzi, 1982DH
38.39273.Nuzzi, 1982DH
41.81283.Nuzzi, 1982DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

7Hydrogen + Phenanthrene = Phenanthrene, tetradecahydro-

By formula: 7H2 + C14H10 = C14H24

Quantity Value Units Method Reference Comment
Δr-565.kJ/molEqkFrye, 1962gas phase

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gudinowicz, Campbell, et al., 1963
Gudinowicz, B.J.; Campbell, R.H.; Adams, J.S., Specific heat measurements of complex saturated hydrocarbons, J. Chem. Eng. Data, 1963, 8, 201-214. [all data]

Nuzzi, 1982
Nuzzi, M., Thermal data and thermodynamic functions of perhydrophenanthrenes, Riv. Combust., 1982, 36, 41-50. [all data]

Rohác, Censký, et al., 2000
Rohác, Vladislav; Censký, Miroslav; Zala, Diana; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Sporka, Karel; Aim, Karel, Vapor Pressure and Liquid Heat Capacity of Perhydroacenaphthylene and Perhydrophenanthrene, J. Chem. Eng. Data, 2000, 45, 6, 1205-1210, https://doi.org/10.1021/je000130n . [all data]

Frye, 1962
Frye, C.G., Equilibria in the hydrogenation of polycyclic aromatics, J. Chem. Eng. Data, 1962, 7, 592-595. [all data]


Notes

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