Phenanthrene, tetradecahydro-
- Formula: C14H24
- Molecular weight: 192.3404
- IUPAC Standard InChI: InChI=1S/C14H24/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h11-14H,1-10H2
- IUPAC Standard InChIKey: GNMCGMFNBARSIY-UHFFFAOYSA-N
- CAS Registry Number: 5743-97-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- Other names: Perhydrophenanthrene; Tetradecahydrophenanthrene; Perhydrophenanthrene, % 5; Perhydrophenanthrene, # 2; Perhydrophenanthrene, # 6; Perhydrophenanthrene, # 1; Perhydrophenanthrene, # 3; Perhydrophenanthrene, # 4; Perhydrophenanthrene, # 7; Perhydrophenanthrene, # 9; Perhydrophenanthrene, # 8
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 330.1 | 313. | Gudinowicz, Campbell, et al., 1963 | T = 313 to 583 K. |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 289.5 | 298. | Nuzzi, 1982 | T = 193 to 403 K. |
| 345.6 | 298. | Nuzzi, 1982 | T = 193 to 403 K. |
| 281.2 | 298. | Nuzzi, 1982 | T = 193 to 403 K. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 55.7 | 470. | EB | Rohác, Censký, et al., 2000 | Based on data from 455. to 551. K.; AC |
Enthalpy of fusion
| ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 11.155 | 313. | Nuzzi, 1982 | DH |
| 10.481 | 273. | Nuzzi, 1982 | DH |
| 11.832 | 283. | Nuzzi, 1982 | DH |
Entropy of fusion
| ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 35.64 | 313. | Nuzzi, 1982 | DH |
| 38.39 | 273. | Nuzzi, 1982 | DH |
| 41.81 | 283. | Nuzzi, 1982 | DH |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
7 +
=
By formula: 7H2 + C14H10 = C14H24
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -565. | kJ/mol | Eqk | Frye, 1962 | gas phase |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gudinowicz, Campbell, et al., 1963
Gudinowicz, B.J.; Campbell, R.H.; Adams, J.S.,
Specific heat measurements of complex saturated hydrocarbons,
J. Chem. Eng. Data, 1963, 8, 201-214. [all data]
Nuzzi, 1982
Nuzzi, M.,
Thermal data and thermodynamic functions of perhydrophenanthrenes,
Riv. Combust., 1982, 36, 41-50. [all data]
Rohác, Censký, et al., 2000
Rohác, Vladislav; Censký, Miroslav; Zala, Diana; Ruzicka, Vlastimil; Ruzicka, Kvetoslav; Sporka, Karel; Aim, Karel,
Vapor Pressure and Liquid Heat Capacity of Perhydroacenaphthylene and Perhydrophenanthrene,
J. Chem. Eng. Data, 2000, 45, 6, 1205-1210, https://doi.org/10.1021/je000130n
. [all data]
Frye, 1962
Frye, C.G.,
Equilibria in the hydrogenation of polycyclic aromatics,
J. Chem. Eng. Data, 1962, 7, 592-595. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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