Hydrazine, 1,1-dimethyl-

• Formula: C₂H₈N₂
• Molecular weight: 60.0983
• IUPAC Standard InChI: InChI=1S/C2H8N2/c1-4(2)3/h3H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: RHUYHJGZWVXEHW-UHFFFAOYSA-N Copy
• CAS Registry Number: 57-14-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • dimethylhydrazine
• Other names: as-Dimethylhydrazine; Dimazin; Dimazine; Hydrazine, N,N-dimethyl-; N,N-Dimethylhydrazine; UDMH; 1,1-Dimethylhydrazine; (CH3)2NNH2; Unsym-dimethylhydrazine; Dimethylhydrazine, unsymmetrical; Dimethylhydrazine, unsym.; 1,1-Dimethylhydrazin; asymmetric Dimethylhydrazine; uns-Dimethylhydrazine; Niesymetryczna dwu metylohydrazyna; Rcra waste number U098; UN 1163; Unsymmetrical dimethylhydrazine; u-Dimethylhydrazine; gem-Dimethylhydrazine; NSC 60517
• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Donald R. Burgess, Jr.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Enthalpy of vaporization

Entropy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of fusion

Entropy of fusion

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donovan, Shomate, et al., 1960
Donovan, T.M.; Shomate, C.H.; McBride, W.R., The heat of combustion of tetramethyltetrazene and 1,1-dimethylhydrazine, J. Phys. Chem., 1960, 64, 281-282. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Aston, Rock, et al., 1952
Aston, J.G.; Rock, E.J.; Isserow, S., The heats of combustion of the methyl substituted hydrazines and some observations on the burning of volatile liquids, J. Am. Chem. Soc., 1952, 74, 2484-24. [all data]

Aston, Wood, et al., 1953
Aston, J.G.; Wood, J.L.; Zolki, T.P., The thermodynamic properties and configuration of unsymmetrical dimethylhydrazine, J. Am. Chem. Soc., 1953, 75, 6202-6204. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

McMillan, 1967
McMillan, J.A., Hydrazine-1,1-Dimethylhydrazine Solid-Liquid Phase Diagram, J. Chem. Eng. Data, 1967, 12, 39. [all data]

Aston, Wood, et al., 1953, 2
Aston, J.G.; Wood, J.L.; Zolki, T.P., The Thermodynamic Properties and Configuration of Unsymmetrical Dimethylhydrazine, J. Am. Chem. Soc., 1953, 75, 6202. [all data]

Aston, Wood, et al., 1953, 3
Aston, J.G.; Wood, J.L.; Zolki, T.P., The thermodynamic properties and configuration of unsymmetrical dimethylhydrazine, J. Am. Chem. Soc., 1953, 75, 6202-62. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Bourret-Courchesne, Ye, et al., 2000
Bourret-Courchesne, E.; Ye, Q.; Peters, D.W.; Arnold, J.; Ahmed, M.; Irvine, S.J.C.; Kanjolia, R.; Smith, L.M.; Rushworth, S.A., Pyrolysis of dimethylhydrazine and its co-pyrolysis with triethylgallium, Journal of Crystal Growth, 2000, 217, 1-2, 47-54, https://doi.org/10.1016/S0022-0248(00)00398-5 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Notes

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• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  Tboil	Boiling point
  Tfus	Fusion (melting) point
  Ttriple	Triple point temperature
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions
  ΔvapS	Entropy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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