n-Hexadecanoic acid

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSRTX-1HP-101HP-5DB-5
Column length (m) 30.60.25.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.220.20.250.32
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.60.70.50.40.
Tend (C) 250.230.200.250.250.
Heat rate (K/min) 2.2.3.4.5.
Initial hold (min) 8. 2.4.2.
Final hold (min) 30.35.15.10.5.
I 1975.1942.1972.2010.1958.
ReferenceBenkaci-Ali, Baaliouamer, et al., 2007Paolini, Muselli, et al., 2007Politeo, Jukic, et al., 2007Quijano, Salamanca, et al., 2007Wu, Zorn, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5HP-5MSHP-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.50.80.60.60.
Tend (C) 250.250.300.250.280.
Heat rate (K/min) 5.3.4.3.3.
Initial hold (min) 2.    
Final hold (min) 5.10.   
I 1971.1963.1963.1979.1971.
ReferenceWu, Zorn, et al., 2007Yu, Liao, et al., 2007Zeng, Zhao, et al., 2007Javidnia, Miri, et al., 2006Kukic J., Petrovic S., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5CP Sil 8 CBDB-5SPB-1DB-1
Column length (m) 30.50.50.30.30.
Carrier gas He N2HeHe
Substrate      
Column diameter (mm) 0.250.320.20.250.25
Phase thickness (μm) 0.25 0.320.250.25
Tstart (C) 60.60.60.50.60.
Tend (C) 250.220.220.250.240.
Heat rate (K/min) 10.4.5.5.4.
Initial hold (min) 2.5.3.3. 
Final hold (min) 10.30.5.15. 
I 1958.1964.1970.1968.1981.
ReferenceLiu J.M., Nan P., et al., 2006Mahadevan and Farmer, 2006Masoudi, Esmaeili, et al., 2006Radulovic, Lazarevic, et al., 2006Rezazadeh, Hamedani, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5MSHP-5MSHP-5
Column length (m) 25.30.30.30.30.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.50.80.60.
Tend (C) 240.280.285.300.250.
Heat rate (K/min) 4.4.4.34.10.
Initial hold (min)  5.  2.
Final hold (min)     10.
I 1973.1969.2003.1995.51970.
ReferenceRezazadeh, Hamedani, et al., 2006Saroglou, Dorizas, et al., 2006Vujisic L., Vuckovic I., et al., 2006Zhao C.X., Li, et al., 2006Zhao J.Y., Liu J.M., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5CP Sil 5 CBCP Sil 5 CBDB-5HP-5
Column length (m) 30.25.25.25.30.
Carrier gas HeH2HeN2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25 0.40.250.25
Tstart (C) 50.80.80.75.60.
Tend (C) 260.270.270.210.260.
Heat rate (K/min) 10.10.10.3.3.
Initial hold (min) 3.  10. 
Final hold (min)    1. 
I 1972.1951.1951.1970.1978.
ReferenceZhao, Wang X.Y., et al., 2006Ziegenbein, Hanssen, et al., 2006Ziegenbein, Hanssen, et al., 2006, 2bin Jantan, Yalvema, et al., 2005Javidnia, Miri, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSDB-5SE-30DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.40.60.40.
Tend (C) 260.250.260.280.250.
Heat rate (K/min) 3.4.2.16.5.
Initial hold (min)  2.5.3.2.
Final hold (min)  20.20.10.5.
I 1970.1991.1968.1979.1958.
ReferenceJavidnia, Miri, et al., 2005, 2Pino, Mesa, et al., 2005Senatore, Napolitano, et al., 2005Tundis, Passalacqua, et al., 2005Wu, Zorn, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSHP-5DB-5SPB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.260.250.250.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 246.280.260.260.250.
Heat rate (K/min) 3.4.3.3.4.
Initial hold (min)  5.  2.
Final hold (min)     20.
I 1960.1972.1968.1967.1973.
ReferenceAdams, Habte, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004Javidnia, Miri, et al., 2004Javidnia, Miri, et al., 2004, 2Píno, Marbot, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5SPB-5Optima 5Optima 5DB-1
Column length (m) 30.30.25.25.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.40.
Tend (C) 250.250.280.280.250.
Heat rate (K/min) 4.4.3.3.2.
Initial hold (min) 2.2.  5.
Final hold (min) 20.20.20.20.20.
I 1973.1972.1994.1949.1956.
ReferencePino, Marbot, et al., 2004Pino, Marbot, et al., 2004, 2Vérité, Nacer, et al., 2004Chosson, Vérité, et al., 2003de Feo, Bruno, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5HP-5MSCP Sil 5 CBSPB-5
Column length (m) 30.25.60.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 60.60.40.60.60.
Tend (C) 280.260.310.280.250.
Heat rate (K/min) 3.4.3.3.4.
Initial hold (min)   1.10.2.
Final hold (min)   20.60.20.
I 1966.1967.1962.1954.1973.
ReferenceFokialakis, Melliou, et al., 2003Javidnia, Miri, et al., 2003Lalel, Singh, et al., 2003Pino, Almora, et al., 2003Pino, Marbot, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-5HP-5MSHP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.330.250.250.250.25
Tstart (C) 40.60.60.50.60.
Tend (C) 260.280.300.280.280.
Heat rate (K/min) 2.4.3.3.3.
Initial hold (min) 5.5. 5.5.
Final hold (min) 20.    
I 1965.1972.1978.1977.1966.
ReferenceSenatore, Rigano, et al., 2003Skaltsa, Demetzos, et al., 2003Couladis, Chinou, et al., 2002Demetzos, Angelopoulou, et al., 2002Fokialakis, Magiatis, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBDB-1SE-30SPB-5CP Sil 5 CB
Column length (m) 50.25.25.30.30.
Carrier gas H2N2N2HeH2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.15 0.250.250.25
Tstart (C) 40.60.60.60.60.
Tend (C) 300.180.180.250.280.
Heat rate (K/min) 4.3.3.4.2.
Initial hold (min) 3.10.10.2.10.
Final hold (min)  10.10.20.40.
I 1962.1938.1938.1973.1952.
ReferenceHeinrich, Pfeifhofer, et al., 2002bin Jantan and bin Ahmad, 2002bin Jantan, Ayop, et al., 2002Pino, Marbot, et al., 2002Pino, Marbot, et al., 2002, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBHP-5DB-5CP Sil 5 CBCP Sil 5 CB
Column length (m) 50.30.30.50.50.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.320.250.250.320.32
Phase thickness (μm) 0.40.250.250.40.4
Tstart (C) 60.60.60.60.60.
Tend (C) 280.280.240.280.280.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min) 10.5. 10.10.
Final hold (min) 60.  60.60.
I 1952.1968.1963.1941.1952.
ReferencePino, Marbot, et al., 2002, 3Aligiannis, Kalpoutzakis, et al., 2001Nogueira, Bittrich, et al., 2001Pino and Marbot, 2001Pino, Marbot, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSSE-54SE-54HP-5HP-5
Column length (m) 30.25.25.30.30.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.250.310.310.250.25
Phase thickness (μm) 0.25  0.250.25
Tstart (C) 60.35.35.50.50.
Tend (C) 280.230.230.280.280.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min) 5.3.3.5.5.
Final hold (min)  10.10.  
I 1972.1998.931999.891972.1962.
ReferenceSkaltsa, Mavrommati, et al., 2001Yin, Xiu, et al., 2001Yin, Xiu, et al., 2001Lazari, Skaltsa, et al., 2000Skaltsa, Lazari, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5BPX-5BPX-5CP Sil 5 CBSE-54
Column length (m) 30.50.50.25.25.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.320.320.250.31
Phase thickness (μm) 0.250.250.25  
Tstart (C) 50.50.50.60.35.
Tend (C) 280.250.250.260.250.
Heat rate (K/min) 4.4.4.5.4.
Initial hold (min) 5.5.5. 3.
Final hold (min)  5.5.  
I 1962.1966.1980.1950.1982.
ReferenceLazari, Skaltsa, et al., 1999Mandin, Duckham, et al., 1999Mandin, Duckham, et al., 1999Weyerstahl, Marschall, et al., 1999Li, Wang, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Ultra-1DB-1DB-1DB-1Ultra-1
Column length (m) 25.30.30.30.25.
Carrier gas He    
Substrate      
Column diameter (mm) 0.320.20.20.20.32
Phase thickness (μm) 0.520.250.250.250.52
Tstart (C) 35.50.50.50.35.
Tend (C) 320.300.300.300.320.
Heat rate (K/min) 15.5.5.5.15.
Initial hold (min)  2.2.2. 
Final hold (min) 10.5.5.5.10.
I 1939.1942.1942.1943.1938.97
ReferenceRichmond and Pombo-Villar, 1998Johnson, Urso, et al., 1997Johnson, Urso, et al., 1997Johnson, Urso, et al., 1997Richmond and Pombo-Villar, 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1HP-101DB-1DB-1
Column length (m) 30.60.50.60.60.
Carrier gas H2HeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm)  0.25 0.250.25
Tstart (C) 60.50.70.40.40.
Tend (C) 220.250.200.280.280.
Heat rate (K/min) 2.3.53.2.2.
Initial hold (min) 3.5. 3.3.
Final hold (min)    10.10.
I 1951.2001.2000.1956.1950.
ReferenceSakho, Chassagne, et al., 1997Stashenko, Prada, et al., 1996Chung, Eiserich, et al., 1993Adedeji, Hartman, et al., 1992Adedeji, Hartman, et al., 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPacked
Active phase DB-1SPB-1SPB-1SE-30
Column length (m) 60.60.60.1.8
Carrier gas HeHeHeN2
Substrate    Chromosorb W
Column diameter (mm) 0.250.250.25 
Phase thickness (μm) 0.250.250.25 
Tstart (C) 40.35.35.130.
Tend (C) 280.235.235.290.
Heat rate (K/min) 2.2.2.8.
Initial hold (min) 3.10.10.2.
Final hold (min) 10.40.40.8.
I 1951.1973.1973.1975.
ReferenceAdedeji, Hartman, et al., 1991Huang, Bruechert, et al., 1987Huang, Bruechert, et al., 1987Perrigo and Peel, 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Benkaci-Ali, Baaliouamer, et al., 2007
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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References