Glycine
- Formula: C2H5NO2
- Molecular weight: 75.0666
- IUPAC Standard InChIKey: DHMQDGOQFOQNFH-UHFFFAOYSA-N
- CAS Registry Number: 56-40-6
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Other names: Acetic acid, amino-; Aciport; Aminoacetic acid; Aminoethanoic acid; Glicoamin; Glycocoll; Glycolixir; Glycosthene; Padil; NH2CH2COOH; Amitone; Glycine, non-medical; Hampshire glycine; Athenon; Gly; Glycine, free base; Gyn-hydralin; 2-Aminoacetic acid; NSC 25936; Corilin (Salt/Mix)
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -527.5 ± 0.5 | kJ/mol | Ccb | Vasil'ev, Borodin, et al., 1991 | ALS |
ΔfH°solid | -528.61 | kJ/mol | Ccr | Ngauv, Sabbah, et al., 1977 | ALS |
ΔfH°solid | -537.2 | kJ/mol | Ccb | Hutchens, Cole, et al., 1963 | ALS |
ΔfH°solid | -528.52 ± 0.42 | kJ/mol | Ccb | Huffman, Fox, et al., 1937 | Author's hf298=-126.69 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -975. ± 8. | kJ/mol | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 103.51 | J/mol*K | N/A | Hutchens, Cole, et al., 1960 | DH |
S°solid,1 bar | 109.2 | J/mol*K | N/A | Parks, Huffman, et al., 1933 | Extrapolation below 90 K, 31.59 J/mol*K.; DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
95. | 298. | Badelin, Kulikov, et al., 1990 | T = 298, 313, 333, 348 K.; DH |
95.1 | 298. | Kulikov, Kozlov, et al., 1989 | T = 298 to 348 K.; DH |
99.3 | 298.15 | Spink and Wads, 1975 | DH |
99.20 | 298.15 | Hutchens, Cole, et al., 1960 | T = 11 to 305 K.; DH |
100.50 | 299.5 | Parks, Huffman, et al., 1933 | T = 93 to 300 K. Value is unsmoothed experimental datum.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vasil'ev, Borodin, et al., 1991
Vasil'ev, V.P.; Borodin, V.A.; Kopnyshev, S.B.,
Calculation of the standard enthalpies of combustion and of formation of crystalline organic acids and complexones from the energy contributions of atomic groups,
Russ. J. Phys. Chem. (Engl. Transl.), 1991, 65, 29-32. [all data]
Ngauv, Sabbah, et al., 1977
Ngauv, S.N.; Sabbah, R.; Laffitte, M.,
Thermodynamique de composes azotes. III. Etude thermochimique de la glycine et de la l-α-alanine,
Thermochim. Acta, 1977, 20, 371-380. [all data]
Hutchens, Cole, et al., 1963
Hutchens, J.O.; Cole, A.G.; Stout, J.W.,
Heat capacities from 11 to 305°K., entropies, and free energies of formation of L-valine, L-isoleucine, and L-leucine,
J. Phys. Chem., 1963, 67, 1128-1130. [all data]
Huffman, Fox, et al., 1937
Huffman, H.M.; Fox, S.W.; Ellis, E.L.,
Thermal data. VII. The heats of combustion of seven amino acids,
J. Am. Chem. Soc., 1937, 59, 2144-21. [all data]
Hutchens, Cole, et al., 1960
Hutchens, J.O.; Cole, A.G.; Stout, J.W.,
Heat capacities from 11 to 305K. and entropies of L-alanine and glycine,
J. Am. Chem. Soc., 1960, 82, 4813-4815. [all data]
Parks, Huffman, et al., 1933
Parks, G.S.; Huffman, H.M.; Barmore, M.,
Thermal data on organic compounds. XI. The heat capacities,
entropies and free energies of ten compounds containing oxygen or nitrogen. J. Am. Chem. Soc., 1933, 55, 2733-2740. [all data]
Badelin, Kulikov, et al., 1990
Badelin, V.G.; Kulikov, O.V.; Batagin, V.S.; Udzig, E.; Zielenkiewicz, A.; Zielenkiewicz, W.; Krestov, G.A.,
Physico-chemical properties of peptides and their solutions,
Thermochim. Acta, 1990, 169, 81-93. [all data]
Kulikov, Kozlov, et al., 1989
Kulikov, O.V.; Kozlov, V.A.; Malenkina, L.I.; Badelin, V.G.,
Heat capacities of amino acids and peptides and excess characteristics ot their aqueous solutions, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo,
Inst. nevod. rast., 1989, Akad. [all data]
Spink and Wads, 1975
Spink, C.H.; Wads, I.,
Thermochemistry of solutions of biochemical model compounds. 4. The partial molar heat capacities of some amino acids in aqueous solution,
J. Chem. Thermodynam., 1975, 7, 561-572. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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