2-Butene, 2,3-dimethyl-
- Formula: C6H12
- Molecular weight: 84.1595
- IUPAC Standard InChIKey: WGLLSSPDPJPLOR-UHFFFAOYSA-N
- CAS Registry Number: 563-79-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Tetramethylethylene; 1,1,2,2-Tetramethylethylene; 2,3-Dimethyl-2-butene; 2,3-Dimethylbut-2-ene; 2,3-Dimethylbutene-2; (CH3)2C=C(CH3)2; Tetramethylethene
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Normal boiling point
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Tboil (K) | Reference | Comment |
---|---|---|
346.4 | Weast and Grasselli, 1989 | BS |
346.4 | Majer and Svoboda, 1985 | |
346.2 | Parnes, Khotimskaya, et al., 1969 | Uncertainty assigned by TRC = 1. K; TRC |
346.39 | Anonymous, 1961 | Uncertainty assigned by TRC = 0.2 K; TRC |
346.15 | Simmons and Smith, 1959 | Uncertainty assigned by TRC = 2. K; TRC |
346.4 | Anonymous, 1957 | Uncertainty assigned by TRC = 0.2 K; TRC |
344.65 | Liu, 1956 | Uncertainty assigned by TRC = 2. K; TRC; Data excluded from overall average |
346. | Milas, Davis, et al., 1955 | Uncertainty assigned by TRC = 4. K; TRC |
346. | Brewster, Patterson, et al., 1954 | Uncertainty assigned by TRC = 2. K; TRC |
345. | Eidus, Puzitskii, et al., 1954 | Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average |
346.15 | Hickinbottom and Hogg, 1954 | Uncertainty assigned by TRC = 0.6 K; TRC |
345.95 | Hickinbottom, Hogg, et al., 1954 | Uncertainty assigned by TRC = 0.5 K; TRC |
346.45 | Kelso, Greenlee, et al., 1952 | Uncertainty assigned by TRC = 0.5 K; TRC |
346.35 | Braun, Spooner, et al., 1950 | Uncertainty assigned by TRC = 0.5 K; TRC |
346.34 | Boord, Henne, et al., 1949 | Uncertainty assigned by TRC = 0.2 K; TRC |
346.53 | Koch, 1948 | Uncertainty assigned by TRC = 0.2 K; TRC |
346.35 | Howard, Mears, et al., 1947 | Uncertainty assigned by TRC = 0.1 K; TRC |
346.25 | Boord, Greenlee, et al., 1946 | Uncertainty assigned by TRC = 0.4 K; TRC |
346.15 | Moldavskii, Nizovkina, et al., 1946 | Uncertainty assigned by TRC = 1. K; TRC |
346.34 | Boord, Perilstein, et al., 1944 | Uncertainty assigned by TRC = 0.2 K; TRC |
346.34 | Anonymous, 1943 | Uncertainty assigned by TRC = 0.3 K; TRC |
346.41 | Fookson, Mears, et al., 1943 | Uncertainty assigned by TRC = 0.15 K; TRC |
346.45 | Amemiya, 1942 | Uncertainty assigned by TRC = 1. K; TRC |
346.15 | Boord, 1942 | Uncertainty assigned by TRC = 1.5 K; TRC |
346.39 | Brooks, Howard, et al., 1940 | Uncertainty assigned by TRC = 0.07 K; TRC |
346.15 | Goldwasser and Taylor, 1939 | Uncertainty assigned by TRC = 0.7 K; TRC |
346.50 | Carr and Walter, 1936 | Uncertainty assigned by TRC = 0.2 K; TRC |
345.9 | Van Risseghem, Gredy, et al., 1933 | Uncertainty assigned by TRC = 2. K; TRC |
346.2 | Schurman and Boord, 1933 | Uncertainty assigned by TRC = 0.4 K; TRC |
346.65 | Brooks and Humphrey, 1918 | Uncertainty assigned by TRC = 2. K; TRC |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Parnes, Khotimskaya, et al., 1969
Parnes, Z.N.; Khotimskaya, G.A.; Kudryavtsev, R.V.; Lukina, M.Y.; Kursanov, D.N.,
The Behavior of Cyclopropane Hydrocarbons in Ionic Hydrogenation Reactions,
Dokl. Akad. Nauk SSSR, Ser. Khim., 1969, 184, 615-8. [all data]
Anonymous, 1961
Anonymous, R.,
Preliminary thermodyn. prop. of FREON-14, E. I. Du Pont, Freon Tech. Bull. T-14, 1961. [all data]
Simmons and Smith, 1959
Simmons, H.E.; Smith, R.D.,
A New Synthesis of Cyclopropanes,
J. Am. Chem. Soc., 1959, 81, 4256. [all data]
Anonymous, 1957
Anonymous, R.,
, Am. Pet. Inst. Res. Proj. 6, Carnegie-Mellon Univ., 1957. [all data]
Liu, 1956
Liu, Y.-C.,
Free Radical Reaction. Reaction of Grignard Reagents with 2-Bromo-2,3- dimethylbutane and with1-Chloro-1-methylcyclohexane in the presence of Condensed Halides,
Huaxue Xuebao, 1956, 22, 104. [all data]
Milas, Davis, et al., 1955
Milas, N.A.; Davis, P.; Nolan, J.T.,
Organic Peroxides XX. Peroxides from the Ozonization of Olefins in the Presence of Carbonium Ions,
J. Am. Chem. Soc., 1955, 77, 2536. [all data]
Brewster, Patterson, et al., 1954
Brewster, J.H.; Patterson, J.W.; Fidler, D.A.,
Reductions at Metal Surfaces III. Clemensen Reduction of Some Sterically- hindered Ketones,
J. Am. Chem. Soc., 1954, 76, 6368. [all data]
Eidus, Puzitskii, et al., 1954
Eidus, Y.T.; Puzitskii, K.V.; Meshcheryakov, A.P.,
Catalytic Hydrocondensation of Carbon Monoxide with Olefins. XI. Behavior of Trimethylethylene and Tetramethylethylene in Hydrocondnsational Catalysis,
Izv. Akad. Nauk SSSR, 1954, 1954, 149-53. [all data]
Hickinbottom and Hogg, 1954
Hickinbottom, W.J.; Hogg, D.R.,
Reaction of Epoxides with Carboxylic Acids,
J. Chem. Soc., 1954, 1954, 4200. [all data]
Hickinbottom, Hogg, et al., 1954
Hickinbottom, W.J.; Hogg, D.R.; Peter; Wood,
J. Chem. Soc., 1954, 1954, 4400. [all data]
Kelso, Greenlee, et al., 1952
Kelso, R.G.; Greenlee, K.W.; Derfer, J.M.; Boord, C.E.,
The Synthesis and Properties of 1,1,2-Trimethylcyclopropane,
J. Am. Chem. Soc., 1952, 74, 287-92. [all data]
Braun, Spooner, et al., 1950
Braun, W.G.; Spooner, D.F.; Fenske, M.R.,
Raman spectra hydrocarbons and oxygenated compounds,
Anal. Chem., 1950, 22, 1074. [all data]
Boord, Henne, et al., 1949
Boord, C.E.; Henne, A.L.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M.,
The Grignard Reagent in hydrocarbon synthesis,
Ind. Eng. Chem., 1949, 41, 609. [all data]
Koch, 1948
Koch, H.,
, Unpublished, Kaiser-Wilhelm Inst. Mulheim, Ruhr, Germany, 1948. [all data]
Howard, Mears, et al., 1947
Howard, F.L.; Mears, T.W.; Fookson, A.; Pomerantz, P.; Brooks, D.B.,
Preparation and physical properties of several aliphatic hydrocarbons and intermediates,
J. Res. Natl. Bur. Stand. (U. S.), 1947, 38, 365. [all data]
Boord, Greenlee, et al., 1946
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L.,
The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Weight, Am. Pet. Inst. Res. Proj. 45, Eighth Annu. Rep., Ohio State Univ., June 30, 1946. [all data]
Moldavskii, Nizovkina, et al., 1946
Moldavskii; Nizovkina; Sharkova,
Zh. Obshch. Khim., 1946, 16, 427. [all data]
Boord, Perilstein, et al., 1944
Boord, C.E.; Perilstein, W.L.; Greenlee, K.W.,
, Am. Pet. Inst. Hydrocarbon Res. Proj., Sixth Annu. Ref., Ohio State Univ., Aug. 31, 1944. [all data]
Anonymous, 1943
Anonymous, R.,
, Sunbury Rep. No. 2176, Anglo-Iranian Oil Co., 1943. [all data]
Fookson, Mears, et al., 1943
Fookson, A.; Mears, T.W.; Glazoff, A.; Howard, F.L.,
, Natl. Advis. Comm. Aeronaut., Special Rep. 12, Natl. Bur. Stand., 1943. [all data]
Amemiya, 1942
Amemiya, T.,
Nippon Kagaku Zasshi, 1942, 63, 1225. [all data]
Boord, 1942
Boord, C.E.,
Oil & Gas J., 1942, 41, 27, 188. [all data]
Brooks, Howard, et al., 1940
Brooks, D.B.; Howard, F.L.; Crafton, H.C.,
Physical Properties of Some Purified Aliphatic Hydrocarbons,
J. Res. Natl. Bur. Stand. (U. S.), 1940, 24, 33. [all data]
Goldwasser and Taylor, 1939
Goldwasser, S.; Taylor, H.S.,
Catalytic dehydration of c6-c8 aliphatic alcohols,
J. Am. Chem. Soc., 1939, 61, 1751. [all data]
Carr and Walter, 1936
Carr, E.P.; Walter, G.F.,
The Ultraviolet Absorption SPectra of Simple Hydrocarbons II. In Liquid and Solution Phase,
J. Chem. Phys., 1936, 4, 756. [all data]
Van Risseghem, Gredy, et al., 1933
Van Risseghem, H.; Gredy, B.; Piaux, I.,
C. R. Hebd. Seances Acad. Sci., 1933, 196, 938. [all data]
Schurman and Boord, 1933
Schurman, I.; Boord, C.E.,
Synthesis in teh Olefin Series V. Completing the Survey of the Hexenes and Including Certain Heptenes and Octenes,
J. Am. Chem. Soc., 1933, 55, 4930-5. [all data]
Brooks and Humphrey, 1918
Brooks, B.T.; Humphrey, I.,
The Action of Concentrated Sulfuric Acid on Olefins, with Particular Reference to the Refining of Petroleum Distillates,
J. Am. Chem. Soc., 1918, 40, 822. [all data]
Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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