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Carbon Tetrachloride

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Carbon Tetrachloride = (Chlorine anion bullet Carbon Tetrachloride)

By formula: Cl- + CCl4 = (Cl- bullet CCl4)

Quantity Value Units Method Reference Comment
Deltar56.1 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar59.4 ± 2.9kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.1kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar24.7 ± 3.8kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B

C8H6MoO3 (solution) + Carbon Tetrachloride (solution) = Molybdenum, tricarbonylchloro(η5-2,4-cyclopentadien-1-yl)- (solution) + Trichloromethane (solution)

By formula: C8H6MoO3 (solution) + CCl4 (solution) = C8H5ClMoO3 (solution) + CHCl3 (solution)

Quantity Value Units Method Reference Comment
Deltar-133.1 ± 3.8kJ/molRSCNolan, López de la Vega, et al., 1986solvent: Tetrahydrofuran; The enthalpy of solution of Mo(Cp)(CO)3(H)(cr) was measured as 8.8 ± 0.4 kJ/mol Nolan, López de la Vega, et al., 1986, 2. Reaction temperature: 323 K; MS

Carbon dioxide + Carbon Tetrachloride = 2Phosgene

By formula: CO2 + CCl4 = 2CCl2O

Quantity Value Units Method Reference Comment
Deltar70. ± 2.kJ/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS
Deltar70. ± 2.kJ/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS

CCl5- + 2Carbon Tetrachloride = C2Cl9-

By formula: CCl5- + 2CCl4 = C2Cl9-

Quantity Value Units Method Reference Comment
Deltar38.9kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.7kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Trichloromethane + Chlorine = Carbon Tetrachloride + Hydrogen chloride

By formula: CHCl3 + Cl2 = CCl4 + HCl

Quantity Value Units Method Reference Comment
Deltar-93.30kJ/molCmKirkbride, 1956liquid phase; Heat of chlorination; ALS

Carbon Tetrachloride + Bromine = bromine chloride + Methane, bromotrichloro-

By formula: CCl4 + Br2 = BrCl + CBrCl3

Quantity Value Units Method Reference Comment
Deltar37. ± 1.kJ/molEqkMendenhall, Golden, et al., 1973gas phase; ALS

C10H12Mo (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2Mo (cr) + 2Trichloromethane (l)

By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Deltar-321.3 ± 4.4kJ/molRSCCalado, Dias, et al., 1979MS

C10H12W (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2W (cr) + 2Trichloromethane (l)

By formula: C10H12W (cr) + 2CCl4 (l) = C10H10Cl2W (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Deltar-301.1 ± 3.4kJ/molRSCCalado, Dias, et al., 1979MS

2Phosgene = Carbon dioxide + Carbon Tetrachloride

By formula: 2CCl2O = CO2 + CCl4

Quantity Value Units Method Reference Comment
Deltar-70. ± 2.kJ/molEqkLord and Pritchard, 1969gas phase; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S., Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes, J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n . [all data]

Dougherty, Dalton, et al., 1974
Dougherty, R.C.; Dalton, J.; Roberts, J.D., SN2 reactions in the gas phase: Structure of the transition state, Org. Mass Spectrom., 1974, 8, 77. [all data]

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Organometal. Chem., 1986, 315, 187. [all data]

Nolan, López de la Vega, et al., 1986, 2
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., Organometallics, 1986, 5, 2529. [all data]

Lord and Pritchard, 1969
Lord, A.; Pritchard, H.O., Thermodynamics of the reaction between carbon dioxide and carbon tetrachloride, J. Chem. Thermodyn., 1969, 1, 495-498. [all data]

Kirkbride, 1956
Kirkbride, F.W., The heats of chlorination of some hydrocarbons and their chloro-derivatives, J. Appl. Chem., 1956, 6, 11-21. [all data]

Mendenhall, Golden, et al., 1973
Mendenhall, G.D.; Golden, D.M.; Benson, S.W., Thermochemistry of the bromination of carbon tetrachloride and the heat of formation of carbon tetrachloride, J. Phys. Chem., 1973, 77, 2707-2709. [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Organometal. Chem., 1979, 174, 77. [all data]


Notes

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