Metanephrine, 3TMS derivative
- Formula: C19H39NO3Si3
- Molecular weight: 413.7744
- IUPAC Standard InChI: InChI=1S/C19H39NO3Si3/c1-20(24(3,4)5)15-19(23-26(9,10)11)16-12-13-17(18(14-16)21-2)22-25(6,7)8/h12-14,19H,15H2,1-11H3
- IUPAC Standard InChIKey: ZUOAVMHEWGXAQS-UHFFFAOYSA-N
- CAS Registry Number: 56114-63-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Silanamine, N-[2-[3-methoxy-4-[(trimethylsilyl)oxy]phenyl]-N,1,1,1-tetramethyl-2-[(trimethylsilyl)oxy]ethyl]-; Benzeneethanamine, 3-methoxy-N-methyl-N-(trimethylsilyl)-β,4-bis[(trimethylsilyl)oxy]-; Benzenemethanol,4-hydroxy-3-methoxy-α-[(methylamino)methyl]-, tris(trimethylsilyl) deriv.; Metanephrine tri-TMS; Metanephrine, tris-TMS; Metanephrine, TMS; DL-Metanephrine, N,O,O'-(trimethylsilyl)-
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | OV-1 | 190. | 1950. | Cashaw, Walsh, et al., 1971 | N2, GasChrom Q; Column length: 2. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | OV-1 | 1938. | Butts, 1972 | He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1907.1 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cashaw, Walsh, et al., 1971
Cashaw, J.L.; Walsh, M.J.; Yamanaka, Y.; Davis, V.E.,
Simultaneous determination of biogenic amines and narcotic alkaloids by gas-liquid chromatography,
J. Chromatogr. Sci., 1971, 9, 2, 98-104, https://doi.org/10.1093/chromsci/9.2.98
. [all data]
Butts, 1972
Butts, W.C.,
Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds,
Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3
. [all data]
Tret'yakov, 2007
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]
Notes
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