Cr(CO)4


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C5CrO5 (g) = C4CrO4 (g) + Carbon monoxide (g)

By formula: C5CrO5 (g) = C4CrO4 (g) + CO (g)

Quantity Value Units Method Reference Comment
Δr33.0kcal/molKinGRayner, Ishikawa, et al., 1991 
Δr40. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990 
Δr25.1 ± 5.0kcal/molKinGFletcher and Rosenfeld, 1988 

C4CrO4 (g) = Carbon monoxide (g) + C3CrO3 (g)

By formula: C4CrO4 (g) = CO (g) + C3CrO3 (g)

Quantity Value Units Method Reference Comment
Δr39.0kcal/molKinGRayner, Ishikawa, et al., 1991 
Δr20. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rayner, Ishikawa, et al., 1991
Rayner, D.M.; Ishikawa, Y.; Brown, C.E.; Hackett, P.A., J. Chem. Phys., 1991, 94, 5471. [all data]

Venkataraman, Hou, et al., 1990
Venkataraman, B.; Hou, H.; Zhang, Z.; Chen, S.; Bandukwalla, G.; Vernon, M., J. Chem. Phys., 1990, 92, 5338. [all data]

Fletcher and Rosenfeld, 1988
Fletcher, R.T.; Rosenfeld, R.N., Recombination of Cr(CO)n with CO: Kinetics and Bond Dissociation Energies, J. Am. Chem. Soc., 1988, 110, 7, 2097, https://doi.org/10.1021/ja00215a014 . [all data]


Notes

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