trans-Bicyclo[3.3.0]octane
- Formula: C8H14
- Molecular weight: 110.1968
- IUPAC Standard InChI: InChI=1S/C8H14/c1-3-7-5-2-6-8(7)4-1/h7-8H,1-6H2/t7-,8-
- IUPAC Standard InChIKey: AEBWATHAIVJLTA-ZKCHVHJHSA-N
- CAS Registry Number: 5597-89-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -109. ± 2. | kJ/mol | Ccb | Chang, McNally, et al., 1970 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -5040. ± 2. | kJ/mol | Ccb | Chang, McNally, et al., 1970 | Corresponding ΔfHºliquid = -109. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -5041.7 ± 5.0 | kJ/mol | Ccb | Barrett and Linstead, 1936 | Reanalyzed by Cox and Pilcher, 1970, Original value = -5037. ± 13. kJ/mol; Corresponding ΔfHºliquid = -107.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 180.3 | 308. | Chang, McNally, et al., 1970 | T = 308, 334 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chang, McNally, et al., 1970
Chang, Sho-ju.; McNally, D.; Shary-Tehrany, S.; Hickey, S.M.J.; Boyd, R.H.,
The heats of combustion and strain energies of bicylo[n.m.O]alkanes,
J. Am. Chem. Soc., 1970, 92, 3109-3118. [all data]
Barrett and Linstead, 1936
Barrett, J.W.; Linstead, R.P.,
Fused carbon rings. Part X. Some fundamental properties of the 0:3:3-bicycloOctane ring,
J. Chem. Soc., 1936, 611-616. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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