Cyclopentene, octafluoro-
- Formula: C5F8
- Molecular weight: 212.0407
- IUPAC Standard InChIKey: YBMDPYAEZDJWNY-UHFFFAOYSA-N
- CAS Registry Number: 559-40-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Octafluorocyclopentene; Perfluorocyclopentene; Cyclopentene, perfluoro; Flon C 1418; Cyclopentene, 1,2,3,3,4,4,5,5-octafluoro-; Fc-c1418
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Phase change data
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 300. | K | N/A | PCR Inc., 1990 | BS |
Tboil | 300. | K | N/A | Henne, 1962 | Uncertainty assigned by TRC = 4. K; TRC |
Tboil | 298.4 | K | N/A | Henne and Latif, 1954 | Uncertainty assigned by TRC = 0.8 K; Apparently calculated from equation fit to vapor pressure data; TRC |
Tboil | 307. | K | N/A | Park, Benning, et al., 1947 | Uncertainty assigned by TRC = 4. K; TRC |
Reaction thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+ = C5ClF8-
By formula: Cl- + C5F8 = C5ClF8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.74 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 34.1 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
+ = C5F8I-
By formula: I- + C5F8 = C5F8I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.84 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 16.9 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
+ = C5BrF8-
By formula: Br- + C5F8 = C5BrF8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 53.1 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 29.5 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
By formula: C5ClF8- + 2C5F8 = C10ClF16-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.02 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 9.83 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
By formula: C5F9- + 2C5F8 = C10F17-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 28.0 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 4.4 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
+ = C5F9-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >125.5 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | S.Huang, Org.Mass Spectrom. 24, 1065 (1989) |
NIST MS number | 279737 |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Henne, 1962
Henne, A.L.,
, 1962. [all data]
Henne and Latif, 1954
Henne, A.L.; Latif, K.A.,
Perfluorinated Alkene, Alkyne, and Cycloalkene,
J. Am. Chem. Soc., 1954, 76, 610-2. [all data]
Park, Benning, et al., 1947
Park, J.D.; Benning, A.F.; Downing, F.B.; Laucius, J.F.; McHarness, R.C.,
Synthesis of Tetrafluoroethylene. Pyrolysis of Monochlorodifluoromethane,
Ind. Eng. Chem., 1947, 39, 343-8. [all data]
Hiraoka, Fujita, et al., 1905
Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N.,
Gas-phase Ion/Molecule Reactions in C5F8,
J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k
. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tboil Boiling point ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.