Diethylzinc

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid18. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcliquid-3372.3 ± 2.1kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Lautsch, Erzberger, et al., 1958 and Cox and Pilcher, 1970.; MS
Δcliquid-3369. ± 13.kJ/molCC-SBLong and Norrish, 1949Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid290.2J/mol*KN/ARabinovich, Nistratov, et al., 1988DH
liquid276.6J/mol*KN/AGibin, Grishnova, et al., 1987DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
194.4298.15Rabinovich, Nistratov, et al., 1988T = 5 to 300 K.; DH
188.9298.15Gibin, Grishnova, et al., 1987T = 18 to 273 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Long and Norrish, 1949
Long, L.H.; Norrish, R.G.W., Phil. Trans. Roy. Soc. (London), 1949, A241, 587. [all data]

Rabinovich, Nistratov, et al., 1988
Rabinovich, I.B.; Nistratov, V.P.; Fedoseev, V.B.; Sheiman, M.S.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Low-temperature specific heat and thermodynamic functions of diethylzinc, Zhur.Fiz. Khim., 1988, 62, 1349-1352. [all data]

Gibin, Grishnova, et al., 1987
Gibin, A.M.; Grishnova, N.D.; Gusev, A.V.; Moiseev, A.N.; Remeshkova, I.I.; Salganskii, Yu.M., Study of the heat capacity of high-purity diethyl zinc at 18-273 K, Vysokochist. Veshchestva, 1987, (6), 28-32. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References