Tris(2-chloroethyl)amine
- Formula: C6H12Cl3N
- Molecular weight: 204.525
- IUPAC Standard InChI: InChI=1S/C6H12Cl3N/c7-1-4-10(5-2-8)6-3-9/h1-6H2
- IUPAC Standard InChIKey: FDAYLTPAFBGXAB-UHFFFAOYSA-N
- CAS Registry Number: 555-77-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: HN3; Trichlormethine; A 8729; Ethanamine, 2-chloro-N,N-bis(2-chloroethyl)-; Sinalost base; SK 100; Tri-2-chloroethylamine; Triethylamine, 2,2',2''-trichloro-; Trimitan base; Tris(β-chloroethyl)amine; TL 145; TS 160; 2,2',2''-Trichlorotriethylamine; Trimustine; Lekamin; NSC-260424; bis(2-chloroethyl)acetaldehyde acetal
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Phase change data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 65.0 | 288. | A,GS | Stephenson and Malanowski, 1987 | Based on data from 273. to 333. K. See also Redemann, Chaikin, et al., 1948 and Dykyj, 1972. |
Gas Chromatography
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Methyl Silicone | 140. | 1361. | Huber, Kenndler, et al., 1993 | H2; Column length: 5. m; Phase thickness: 2.65 μm |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | PEG-20M | 160. | 2089. | Huber, Kenndler, et al., 1993 | Column length: 10. m; Phase thickness: 1.33 μm |
| Capillary | PEG-20M | 180. | 2101. | Huber, Kenndler, et al., 1993 | Column length: 10. m; Phase thickness: 1.33 μm |
| Capillary | PEG-20M | 130. | 2070.4 | Huber, Kenndler, et al., 1993 | Column length: 10. m; Phase thickness: 1.33 μm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 1411. | Kostiainen, 2000 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min, 280. C @ 10. min |
| Capillary | SE-54 | 1403.83 | Kaipainen, Kostiainen, et al., 1992 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min; Tend: 280. C |
| Capillary | SE-54 | 1405.37 | Kaipainen, Kostiainen, et al., 1992 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min; Tend: 280. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Polydimethyl siloxane | 1405. | Staples, 2006 | Program: not specified |
| Capillary | 5 % Phenyl methyl siloxane | 1411. | OPCW, 1997 | Program: not specified |
References
Go To: Top, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Redemann, Chaikin, et al., 1948
Redemann, C. Ernst; Chaikin, Saul W.; Fearing, Ralph B.,
The Volatility and Vapor Pressure of Ten Substituted 2-Chloroethylamines 1,
J. Am. Chem. Soc., 1948, 70, 4, 1648-1650, https://doi.org/10.1021/ja01184a102
. [all data]
Dykyj, 1972
Dykyj, J.,
Petrochemia, 1972, 12, 1, 13. [all data]
Huber, Kenndler, et al., 1993
Huber, J.F.K.; Kenndler, E.; Reich, G.; Hack, W.; Wolf, J.,
Optimal Selection of Gas Chromatographic Columns for the Analytical Control of Chemical Warfare Agents by Application of Information Theory to Retention Data,
Anal. Chem., 1993, 65, 20, 2903-2906, https://doi.org/10.1021/ac00068a031
. [all data]
Kostiainen, 2000
Kostiainen, O.,
Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention
in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]
Kaipainen, Kostiainen, et al., 1992
Kaipainen, A.; Kostiainen, O.; Riekkola, M.-L.,
Identification of chemical warfare agents in air samples using capillary column gas chromatography with three simultaneous detectors,
J. Microcolumn Sep., 1992, 4, 3, 245-251, https://doi.org/10.1002/mcs.1220040311
. [all data]
Staples, 2006
Staples, E.J.,
Creating a compound library for chemical warfare agents for the ZNose, 2006, retrieved from http://www.estcal.com/TechPapers/Security/CWA-Libraries.pdf. [all data]
OPCW, 1997
OPCW,
Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/cseries/csp1/CIDEC64.html. [all data]
Notes
Go To: Top, Phase change data, Gas Chromatography, References
- Symbols used in this document:
ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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