Morphine, 2TMS derivative

• Formula: C₂₃H₃₅NO₃Si₂
• Molecular weight: 429.6999
• IUPAC Standard InChI: InChI=1S/C23H35NO3Si2/c1-24-13-12-23-16-9-11-19(27-29(5,6)7)22(23)25-21-18(26-28(2,3)4)10-8-15(20(21)23)14-17(16)24/h8-11,16-17,19,22H,12-14H2,1-7H3 Copy

  
• IUPAC Standard InChIKey: WGFFZYSWLVJOLB-UHFFFAOYSA-N Copy
• CAS Registry Number: 55449-66-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Species with the same structure:
  • Morphine, bis(trimethylsilyl) ether
• Other names: Morphinan, 7,8-didehydro-4,5-epoxy-17-methyl-3,6-bis[(trimethylsilyl)oxy]-, (5α,6α)-; Morphine, bis(trimethylsilyl)-; Morphine di-TMS derivative; Morphine bis-O-TMS; Morphine, bis-TMS; Morphine, diTMS; Morphine, bis(trimethylsilyl) derivative; Morphine, TMS; Hydromorphone, bis-TMS; Hydromorphone bis-O-TMS; Hydromorphone TMS
• Information on this page:
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Options:
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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lora-Tamayo, Rams, et al., 1986
Lora-Tamayo, C.; Rams, M.A.; Chacon, J.M.R., Gas Chromatographic Data for 187 Nitrogen- or Phosphorus-Containing Drugs and Metabolites of Toxicological Interest Analysed on Methyl Silicone Capillary Columns, J. Chromatogr., 1986, 374, 73-85, https://doi.org/10.1016/S0378-4347(00)83254-5 . [all data]

Cashaw, Walsh, et al., 1971
Cashaw, J.L.; Walsh, M.J.; Yamanaka, Y.; Davis, V.E., Simultaneous determination of biogenic amines and narcotic alkaloids by gas-liquid chromatography, J. Chromatogr. Sci., 1971, 9, 2, 98-104, https://doi.org/10.1093/chromsci/9.2.98 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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