4,4'-Bipyridine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid44.65 ± 0.53kcal/molCcbRibeiro da Silva, Morais, et al., 1995 
Quantity Value Units Method Reference Comment
Δcsolid-1258.4 ± 0.43kcal/molCcbRibeiro da Silva, Morais, et al., 1995 

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil578.2KN/AWeast and Grasselli, 1989BS
Tboil578.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Δvap17.0 ± 0.62kcal/molCGCLipkind and Chickos, 2009See also Lipkind, Hanshaw, et al., 2009.; AC
Quantity Value Units Method Reference Comment
Δsub25.41 ± 0.67kcal/molCRibeiro da Silva, Morais, et al., 1995ALS
Δsub25.41kcal/molN/ARibeiro da Silva, Morais, et al., 1995DRB
Δsub25.41 ± 0.67kcal/molCRibeiro da Silva, Morais, et al., 1995AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
3.85377.5DSCLipkind, Hanshaw, et al., 2009AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Morais, et al., 1995
Ribeiro da Silva, M.A.V.; Morais, V.M.F.; Matos, M.A.R.; Rio, C.M.A., Thermochemical and theoretical studies of some bipyridines, J. Org. Chem., 1995, 60, 5291-5294. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Lipkind and Chickos, 2009
Lipkind, D.; Chickos, J.S., , Abstract from 38th Great Lakes Regional Meeting of the American Chemical Society, May 13-16, Chicago, IL, 2009, GLRM-275. [all data]

Lipkind, Hanshaw, et al., 2009
Lipkind, Dmitri; Hanshaw, William; Chickos, James S., Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Heterocycles and Related Compounds, J. Chem. Eng. Data, 2009, 54, 10, 2930-2943, https://doi.org/10.1021/je900034d . [all data]


Notes

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