SiH2 radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr357.2 ± 1.4kcal/molD-EAKasdan, Herbst, et al., 1975gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

(H2Si- • 4294967295Silylidyne) + Silylidyne = H2Si-

By formula: (H2Si- • 4294967295HSi) + HSi = H2Si-

Quantity Value Units Method Reference Comment
Δr83.4 ± 2.3kcal/molN/AKasdan, Herbst, et al., 1975gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]


Notes

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