SiH2 radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas165. ± 5.4kJ/molR-EAKasdan, Herbst, et al., 1975 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(H2Si- • 4294967295Silylidyne) + Silylidyne = H2Si-

By formula: (H2Si- • 4294967295HSi) + HSi = H2Si-

Quantity Value Units Method Reference Comment
Δr349. ± 9.6kJ/molN/AKasdan, Herbst, et al., 1975gas phase

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr1495. ± 5.9kJ/molD-EAKasdan, Herbst, et al., 1975gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr1495. ± 5.9kJ/molD-EAKasdan, Herbst, et al., 1975gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(H2Si- • 4294967295Silylidyne) + Silylidyne = H2Si-

By formula: (H2Si- • 4294967295HSi) + HSi = H2Si-

Quantity Value Units Method Reference Comment
Δr349. ± 9.6kJ/molN/AKasdan, Herbst, et al., 1975gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]


Notes

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