SiH2 radical anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(H2Si- • 4294967295Silylidyne) + Silylidyne = H2Si-

By formula: (H2Si- • 4294967295HSi) + HSi = H2Si-

Quantity Value Units Method Reference Comment
Δr83.4 ± 2.3kcal/molN/AKasdan, Herbst, et al., 1975gas phase

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr357.2 ± 1.4kcal/molD-EAKasdan, Herbst, et al., 1975gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr357.2 ± 1.4kcal/molD-EAKasdan, Herbst, et al., 1975gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]


Notes

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