Molybdenum anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas140.0 ± 6.4kcal/molAcidBilodeau, Scheer, et al., 1998B
Quantity Value Units Method Reference Comment
gas,1 bar43.181cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Mo- + Hydrogen cation = HMo

By formula: Mo- + H+ = HMo

Quantity Value Units Method Reference Comment
Δr345.8 ± 4.5kcal/molD-EABilodeau, Scheer, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Δr335.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

Mo- + Hydrogen cation = HMo

By formula: Mo- + H+ = HMo

Quantity Value Units Method Reference Comment
Δr345.8 ± 4.5kcal/molD-EABilodeau, Scheer, et al., 1998gas phase
Quantity Value Units Method Reference Comment
Δr335.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bilodeau, Scheer, et al., 1998
Bilodeau, R.C.; Scheer, M.; Haugen, H.K., Infrared Laser Photodetachment of Transition Metal Negative Ions: Studies on Cr-, Mo-, Cu-, and Ag-, J. Phys. B: Atom. Mol. Opt. Phys., 1998, 31, 17, 3885-3891, https://doi.org/10.1088/0953-4075/31/17/013 . [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]


Notes

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