Dimethylzinc
- Formula: C2H6Zn
- Molecular weight: 95.45
- IUPAC Standard InChI: InChI=1S/2CH3.Zn/h2*1H3;
- IUPAC Standard InChIKey: AXAZMDOAUQTMOW-UHFFFAOYSA-N
- CAS Registry Number: 544-97-8
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 13.2 ± 1.4 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | 12.6 ± 0.31 | kcal/mol | Review | Martinho Simões |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(l) + (
• 100
) (solution) = 2
(g) + (
• 100
) (solution)
By formula: C2H6Zn (l) + (H2O4S • 100H2O) (solution) = 2CH4 (g) + (O4SZn • 100H2O) (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -81.7 ± 0.2 | kcal/mol | RSC | Carson, Hartley, et al., 1949 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
(g) =
(g) +
(g)
By formula: C2H6Zn (g) = CH3Zn (g) + CH4 (g)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 63.7 ± 1.5 | kcal/mol | KinG | Jackson, 1989 | |
| ΔrH° | 66.0 to 71.2 | kcal/mol | N/A | Smith and Patrick, 1983 | |
| ΔrH° | 68.0 ± 4.0 | kcal/mol | N/A | McMillen and Golden, 1982 |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Carson, Hartley, et al., 1949
Carson, A.S.; Hartley, K.; Skinner, H.A.,
Thermochemistry of metal alkyls. Part II.?The bond dissociation energies of some Zn?C and Cd?C bonds, and of Et?I.,
Trans. Faraday Soc., 1949, 45, 1159, https://doi.org/10.1039/tf9494501159
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Jackson, 1989
Jackson, R.L.,
Chem. Phys. Lett., 1989, 163, 315. [all data]
Smith and Patrick, 1983
Smith, G.P.; Patrick, R.,
Int. J. Chem. Kinet., 1983, 15, 167. [all data]
McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M.,
Hydrocarbon bond dissociation energies,
Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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