Anthracene-maleic anhydride Diels-Alder adduct

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-100. ± 1.5kcal/molCcbKar, Lenz, et al., 1992 
Quantity Value Units Method Reference Comment
Δcsolid-2002.9 ± 1.4kcal/molCcbKar, Lenz, et al., 1992Corresponding Δfsolid = -99.95 kcal/mol (simple calculation by NIST; no Washburn corrections)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Maleic anhydride + Anthracene = Anthracene-maleic anhydride Diels-Alder adduct

By formula: C4H2O3 + C14H10 = C18H12O3

Quantity Value Units Method Reference Comment
Δr-22. ± 0.5kcal/molCmKiselev, Mavrin, et al., 1982liquid phase; solvent: Benzene
Δr-22.4kcal/molEqkLenz, Hegedus, et al., 1982liquid phase; solvent: 1,2,4-C6H3Cl3

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kar, Lenz, et al., 1992
Kar, M.; Lenz, T.G.; Vaughan, J.D., Thermodynamic measurements for the Diels-Alder adduct of anthracene and maleic anhydride, J. Chem. Thermodyn., 1992, 24, 151-157. [all data]

Kiselev, Mavrin, et al., 1982
Kiselev, V.D.; Mavrin, G.V.; Konovalov, A.I., Thermodynamic principles of the occurrence of a Diels-Alder reaction in the presence of a Lewis acid, Zh. Org. Khim., 1982, 18, 2505-2510. [all data]

Lenz, Hegedus, et al., 1982
Lenz, T.G.; Hegedus, L.S.; Vaughan, J.D., Liquid phase thermochemical energy conversion systems - an application of Diels-Alder chemistry, Int. J. Energy Res., 1982, 6, 357-365. [all data]


Notes

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