Carbonochloridic acid, ethyl ester

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-497.3 ± 1.7kJ/molCmDavies, Finch, et al., 1980Heat of hydrolysis
Quantity Value Units Method Reference Comment
Δcliquid-1370. ± 4.kJ/molCcbSmith, Bjellerup, et al., 1953 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil366.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tc508.15KN/AGuye and Mallet, 1902Uncertainty assigned by TRC = 10. K; this a minimum value, measurement not made because of explosion of sample; TRC
Quantity Value Units Method Reference Comment
Δvap37.86 ± 0.29kJ/molVDavies, Finch, et al., 1980Heat of hydrolysis; ALS
Δvap37.8 ± 0.2kJ/molBGHugh Davies, Finch, et al., 1980Based on data from 281. to 286. K.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
38.7 ± 0.2283.BGHugh Davies, Finch, et al., 1980Based on data from 281. to 286. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Davies, Finch, et al., 1980
Davies, R.H.; Finch, A.; Gardner, P.J., The standard enthalpy of formation of liquid and gaseous ethylchloroformate (C3H5O2Cl), J. Chem. Thermodyn., 1980, 12, 291-296. [all data]

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Guye and Mallet, 1902
Guye, P.A.; Mallet, E., Measurement of Critical Constants, Arch. Sci. Phys. Nat., 1902, 13, 274-296. [all data]

Hugh Davies, Finch, et al., 1980
Hugh Davies, R.; Finch, Arthur; Gardner, P.J., The standard enthalpy of formation of liquid and gaseous ethylchloroformate (C3H5O2Cl), The Journal of Chemical Thermodynamics, 1980, 12, 3, 291-296, https://doi.org/10.1016/0021-9614(80)90049-X . [all data]


Notes

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