Butane, 1,1-dichloro-
- Formula: C4H8Cl2
- Molecular weight: 127.012
- IUPAC Standard InChI: InChI=1S/C4H8Cl2/c1-2-3-4(5)6/h4H,2-3H2,1H3
- IUPAC Standard InChIKey: SEQRDAAUNCRFIT-UHFFFAOYSA-N
- CAS Registry Number: 541-33-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Butylidene chloride; 1,1-Dichlorobutane
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Reaction thermochemistry data
Go To: Top, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
+
By formula: C4H8Cl2 = C4H7Cl + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 61.1 | kJ/mol | Eqk | Levanova, Rodova, et al., 1974 | gas phase |
| ΔrH° | 61.1 ± 0.4 | kJ/mol | Eqk | Rodova, Shevtsova, et al., 1974 | gas phase |
=
+
By formula: C4H8Cl2 = C4H7Cl + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 64.0 ± 0.4 | kJ/mol | Eqk | Rodova, Shevtsova, et al., 1974 | gas phase |
Henry's Law data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
| k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference |
|---|---|---|---|
| 0.13 | V | N/A |
References
Go To: Top, Reaction thermochemistry data, Henry's Law data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Levanova, Rodova, et al., 1974
Levanova, S.V.; Rodova, R.M.; Rozhnov, A.M.; Shevtsova, L.A.,
Thermodynamic calculation of the equilibrium composition of chlorobutene mixtures,
Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 1113-1114. [all data]
Rodova, Shevtsova, et al., 1974
Rodova, R.M.; Shevtsova, L.A.; Levanova, S.V.; Rozhnov, A.M.; Garkushin, I.K.,
Dehydrochlorination of 1,1-dichlorobutane and isomerization of chlorobutenes,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1974, 17, 379-381. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Henry's Law data, References
- Symbols used in this document:
d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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