OsF4 radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.87 ± 0.25TDEqKuznetsov, Korobov, et al., 1989VF4- + OsF4 <=> OsF4- + VF4, ΔH = -7.2±1.2 kcal/mol.

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

Fluorine anion + F4Os = (Fluorine anion • F4Os)

By formula: F- + F4Os = (F- • F4Os)

Quantity Value Units Method Reference Comment
Δr87.0 ± 6.4kcal/molTDEqKuznetsov, Korobov, et al., 1989, 2gas phase; Fluoride Affinity: 0.2±2.6 kcal/mol < VF4

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N.; Savinova, L.N.; Shipachev, V.A.; Mit'kin, V.N., Gas Phase Negative Ions of Platinum Metal Fluorides. I. Electron Affinity of Platinum Metal Tetrafluorides, Int. J. Mass Spectrom. Ion Proc., 1989, 87, 1, 1, https://doi.org/10.1016/0168-1176(89)80001-1 . [all data]

Kuznetsov, Korobov, et al., 1989, 2
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N., Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides., Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7 . [all data]


Notes

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