Cyclopentasiloxane, decamethyl-
- Formula: C10H30O5Si5
- Molecular weight: 370.7697
- IUPAC Standard InChIKey: XMSXQFUHVRWGNA-UHFFFAOYSA-N
- CAS Registry Number: 541-02-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Decamethylcyclopentasiloxane; Dimethylsiloxane pentamer; Dekamethylcyklopentasiloxan; CD3770; D3770; Decamethylcylopentasiloxane
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IR Spectrum
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | DOW CORNING CORP. |
Source reference | COBLENTZ NO. 5518 |
Date | 1965/02/01 |
Name(s) | 2,2,4,4,6,6,8,8,10,10-decamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane |
State | SOLUTION (5% IN CCl4 FOR 3800-1270, 2% IN CS2 FOR 1270-625, AND 5% IN CCl4 FOR 625-210 CM-1) |
Instrument | PERKIN-ELMER 521 (GRATING) |
Instrument parameters | FILTERS AT 3150, 2500, 2000, 1150, 700, 410. GRATING CHANGES: 2000, 630 CM-1 |
Path length | 0.011 CM, 0.011 CM, AND 0.020 CM |
Resolution | 2 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS) |
Boiling point | 210 C |
Gas Chromatography
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Ultra-1 | 1166. | Richmond and Pombo-Villar, 1998 | 25. m/0.32 mm/0.52 μm, He, 15. K/min, 320. C @ 10. min; Tstart: 35. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | VF-5MS | 1215.1 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
Normal alkane RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | SE-30 | 110. | 1164. | Garzo and Alexander, 1971 | Chromosorb G AW DMCS (80-100 mesh); Column length: 3.5 m |
Packed | SE-30 | 125. | 1160. | Garzo and Alexander, 1971 | Chromosorb G AW DMCS (80-100 mesh); Column length: 3.5 m |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SP-2100 | 1165. | Fischer and Kusch, 1993 | He, 40. C @ 3. min, 5. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tend: 280. C |
Capillary | Methyl Silicone | 1184. | Fujimoto, Ohtani, et al., 1990 | 25. m/0.25 mm/0.1 μm, He, 5. K/min; Tstart: 40. C; Tend: 350. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Ultra-1 | 1169. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1172. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1173. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1176. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1183. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1183. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 1161. | Richmond and Pombo-Villar, 1998 | 25. m/0.32 mm/0.52 μm, He; Program: not specified |
Lee's RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 193.3 | Fuentes, Font, et al., 2007 | Column length: 60. m; Program: not specified |
References
Go To: Top, IR Spectrum, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Richmond and Pombo-Villar, 1998
Richmond, R.; Pombo-Villar, E.,
Short communication. Use of persistent trace gas chromatography artifacts for the calculation of pseudo-Sadtler retention indices,
J. Chromatogr. A, 1998, 811, 1-2, 241-245, https://doi.org/10.1016/S0021-9673(98)00285-4
. [all data]
Tret'yakov, 2007
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]
Garzo and Alexander, 1971
Garzo, G.; Alexander, G.,
Gas chromatographic retention characteristics of low molecular weight linear, cyclic and polycyclic methylpolysiloxanes,
Chromatographia, 1971, 4, 12, 554-560, https://doi.org/10.1007/BF02317591
. [all data]
Fischer and Kusch, 1993
Fischer, G.W.; Kusch, P.,
An Automated Curie-Point Pyrolysis-High Resolution Gas Chromatography System,
LC-GC Int., 1993, 6, 12, 760-763. [all data]
Fujimoto, Ohtani, et al., 1990
Fujimoto, S.; Ohtani, H.; Yamagiwa, K.; Tsuge, S.,
Study on retention behavior of cyclic siloxanes by high resolution pyrolysis-gas chromatography with a fused silica capillary column,
J. Hi. Res. Chromatogr., 1990, 13, 6, 397-404, https://doi.org/10.1002/jhrc.1240130603
. [all data]
Kazuyoshi, Seiichi, et al., 2000
Kazuyoshi, N.; Seiichi, Y.; Kazuo, K.; Katsumi, I.; Okihiko, S.,
Polymer analysis by improved pyrolysis gas chromatography hyphenated with four specific detectors,
J. Soc. Cosmet. Chem. Jpn., 2000, 34, 2, 142-151, https://doi.org/10.5107/sccj.34.142
. [all data]
Fuentes, Font, et al., 2007
Fuentes, M.J.; Font, R.; Gomez-Rico, M.F.; Martin-Gullon, I.,
Pyrolysis and combustion of waste lubricant oil from diesel cars: Decomposition and pollutants,
J. Anal. Appl. Pyrolysis, 2007, 79, 1-2, 215-226, https://doi.org/10.1016/j.jaap.2006.12.004
. [all data]
Notes
Go To: Top, IR Spectrum, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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