t-Butyl nitrite

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil336.2KN/AWeast and Grasselli, 1989BS
Tboil336.KN/AAmerican Tokyo Kasei, 1988BS
Tboil334. to 336.KN/AFrinton Laboratories Inc., 1986BS
Quantity Value Units Method Reference Comment
Δvap8.2kcal/molEBatt, Christie, et al., 1974ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
7.36282.AStephenson and Malanowski, 1987Based on data from 267. to 337. K. See also Thompson and Dainton, 1937.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)206.5kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity198.7kcal/molN/AHunter and Lias, 1998 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Frinton Laboratories Inc., 1986
Frinton Laboratories Inc., Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]

Batt, Christie, et al., 1974
Batt, L.; Christie, K.; Milne, R.T.; Summers, A.J., Heats of formation of C1-C4 alkyl nitrites (RONO) and their RO-NO bond dissociation energies, Int. J. Chem. Kinet., 1974, 6, 877-886. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Thompson and Dainton, 1937
Thompson, H.W.; Dainton, F.S., The photochemistry of alkyl nitrites. III, Trans. Faraday Soc., 1937, 33, 1546, https://doi.org/10.1039/tf9373301546 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

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