Chloroacetic acid, propyl ester

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-467.4 ± 4.6kJ/molCcbBjellerup and Smith, 1954Heat of formation derived by Cox and Pilcher, 1970

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-516. ± 2.kJ/molCcrBjellerup and Smith, 1954At 293 K
Quantity Value Units Method Reference Comment
Δcliquid-2762. ± 2.kJ/molCcrBjellerup and Smith, 1954At 293 K
Δcliquid-2761.9 ± 8.4kJ/molCcrSmith, Bjellerup, et al., 1953Reanalyzed by Cox and Pilcher, 1970, Original value = -2754.7 ± 1.1 kJ/mol
Δcliquid-2753.kJ/molCcbSchjanberg, 1935 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
48.5293.VBjellerup and Smith, 1954Heat of formation derived by Cox and Pilcher, 1970; ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
13.0240.Mido, Katano, et al., 1990AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bjellerup and Smith, 1954
Bjellerup, L.; Smith, L., Heats of combustion of some organic chloro-compounds, Kgl. Fysiograph. Sallskap. Lund Forh., 1954, 24, 1-13. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Schjanberg, 1935
Schjanberg, E., Die Verbrennungswarmen und die Refraktionsdaten einiger chlorsubstituierter Fettsauren und Ester., Z. Phys. Chem. Abt. A, 1935, 172, 197-233. [all data]

Mido, Katano, et al., 1990
Mido, Yoshiyuki.; Katano, Hajime.; Isono, Takahiro.; Hashimoto, Masao.; Matsuura, Hiroatsu., Conformational phase transitions of n-propyl chloroacetate: thermal, chlorine-35 nuclear quadrupole resonance, and vibrational spectroscopic studies, J. Phys. Chem., 1990, 94, 21, 8070-8072, https://doi.org/10.1021/j100384a018 . [all data]


Notes

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