Benzoic acid, 3-chloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus427.4KN/AAndrews, Lynn, et al., 1926Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Δsub102.5 ± 0.5kJ/molMERibeiro da Silva and Santos, 2004Based on data from 320. - 340. K.; AC
Δsub101.4 ± 0.4kJ/molCSabbah and Aguilar, 1995AC
Δsub101.4 ± 0.4kJ/molCSabbah and Rojas Aguilar, 1995HCl(1:600 H2O); ALS
Δsub105.8kJ/molCAdedeji, Lalage, et al., 1975AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
101.2 ± 0.4330.MERibeiro da Silva, Fonseca, et al., 2005Based on data from 320. - 340. K.; AC
99.6413.CAdedeji, Lalage, et al., 1975AC
81. ± 2.328.VWolf and Weghofer, 1938ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
22.000427.83N/ASabbath and Hirtz, 1991DH
23.67427.9DSCRibeiro da Silva, Fonseca, et al., 2005AC
23.85427.4N/AAcree, 1991AC
22.0427.8N/ASabbah and Hirtz, 1991AC
23.850427.4N/AAndrews, Lynn, et al., 1926, 2DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
55.8427.4Andrews, Lynn, et al., 1926, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The Heat Capacities and Heat of Crystallization of Some Isomeric Aromatic Compounds, J. Am. Chem. Soc., 1926, 48, 1274. [all data]

Ribeiro da Silva and Santos, 2004
Ribeiro da Silva, Manuel A.V.; Santos, Luis M.N.B.F., Standard molar enthalpy of formation of monothiodibenzoylmethane by rotating-bomb calorimetry, The Journal of Chemical Thermodynamics, 2004, 36, 6, 447-451, https://doi.org/10.1016/j.jct.2004.02.007 . [all data]

Sabbah and Aguilar, 1995
Sabbah, Raphaël; Aguilar, Aaron Rojas, Étude thermodynamique des trois isomères de l'acide chlorobenzoïque. Partie II, Can. J. Chem., 1995, 73, 9, 1538-1545, https://doi.org/10.1139/v95-191 . [all data]

Sabbah and Rojas Aguilar, 1995
Sabbah, R.; Rojas Aguilar, A., Etude thermodynamique des trois isomeres de l'acide chlorobenzoique. Partie II, Can. J. Chem., 1995, 73, 1538-1545. [all data]

Adedeji, Lalage, et al., 1975
Adedeji, Festus A.; Lalage, D.; Brown, S.; Connor, Joseph A.; Leung, May L.; Paz-Andrade, I. Maria; Skinner, Henry A., Thermochemistry of arene chromium tricarbonyls and the strenghts of arene-chromium bonds, Journal of Organometallic Chemistry, 1975, 97, 2, 221-228, https://doi.org/10.1016/S0022-328X(00)89468-1 . [all data]

Ribeiro da Silva, Fonseca, et al., 2005
Ribeiro da Silva, Manuel A.V.; Fonseca, José M.S.; Carvalho, Rui P.B.M.; Monte, Manuel J.S., Thermodynamic study of the sublimation of six halobenzoic acids, The Journal of Chemical Thermodynamics, 2005, 37, 3, 271-279, https://doi.org/10.1016/j.jct.2004.09.005 . [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Sabbath and Hirtz, 1991
Sabbath, R.; Hirtz, H., Etude thermodynamique des trois acides chlorobenzoiques, 1991, Bull. [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Sabbah and Hirtz, 1991
Sabbah, R.; Hirtz, H., Thermodynamic study of chlorobenzoic acids, Bull. Soc. Chim. Fr., 1991, 26. [all data]

Andrews, Lynn, et al., 1926, 2
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]


Notes

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