Adenosine, 4TMS derivative

• Formula: C₂₂H₄₅N₅O₄Si₄
• Molecular weight: 555.9658
• IUPAC Standard InChI: InChI=1S/C22H45N5O4Si4/c1-32(2,3)26-20-17-21(24-14-23-20)27(15-25-17)22-19(31-35(10,11)12)18(30-34(7,8)9)16(29-22)13-28-33(4,5)6/h14-16,18-19,22H,13H2,1-12H3,(H,23,24,26)/t16-,18-,19-,22-/m1/s1 Copy

  
• IUPAC Standard InChIKey: ADQCPBJKGAVWKS-WGQQHEPDSA-N Copy
• CAS Registry Number: 53294-33-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Adenosine-tetrakis(trimethylsilyl)-; Adenosine-tetra-TMS; Adenine riboside, (4TMS); Adenosine, 2',3',5',N6-tetrakis(O-TMSi); Adenosine, (4TMS); N6-TMS-Adenosine, 2',3',5'-tris-O-TMS; Adenosine, N-(trimethylsilyl)-2',3',5'-tris-O-(trimethylsilyl)-; Adenosine, N,O,O,O TMS-; adenosine, TMS; Adenine riboside, TMS; Adenosine, N,O-4TMS
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• Information on this page:
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quilliam, Ogilvie, et al., 1980
Quilliam, M.A.; Ogilvie, K.K.; Sadana, K.L.; Westmore, J.B., Gas chromatographic retention data for silyl and acyl derivatives of nucleosides, J. Chromatogr., 1980, 196, 3, 367-378, https://doi.org/10.1016/S0021-9673(00)84739-1 . [all data]

Quilliam and Westmore, 1978
Quilliam, M.A.; Westmore, J.B., Sterically crowded trialkylsilyl derivatives for chromatography and mass spectrometry of biologically-important compounds, Anal. Chem., 1978, 50, 1, 59-68, https://doi.org/10.1021/ac50023a020 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Andriamaharavo, 2014
Andriamaharavo, N.R., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]

Butts, 1970
Butts, W.C., Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine, J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474 . [all data]

Cao, Aa, et al., 2011
Cao, B.; Aa, J.; Wang, G.; Wu, X.; Liu, L.; Li, M.; Shi, J.; Wang, X.; Zhao, C.; Zheng, T.; Guo, S.; Duan, J., GC-TOFMS analysis of metabolites in adherent MDCK cells and a movel strategy for identifying intracellular metabolic markers for use as cell amount indicators in data normalization, Anal. Bioanal. Chem., 2011, 400, 9, 2983-2993, https://doi.org/10.1007/s00216-011-4981-8 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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