PCl3+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 67050 ± 320 gas Cox, Evans, et al., 1972
Nicholson and Rademacher, 1974

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 37840 ± 320 gas Cox, Evans, et al., 1972
Berkosky, Ellison, et al., 1973
Nicholson and Rademacher, 1974
Tx = 18200 gas E-C Boyle, Jarvis, et al., 1998
gas E-B,A 320 450 Boyle, Jarvis, et al., 1998
Boyle, Jarvis, et al., 1998
gas E-C 500 600 Boyle, Jarvis, et al., 1998

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 30010 ± 320 gas Cox, Evans, et al., 1972
Berkosky, Ellison, et al., 1973
Nicholson and Rademacher, 1974

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 19850 ± 320 gas Cox, Evans, et al., 1972
Berkosky, Ellison, et al., 1973
Nicholson and Rademacher, 1974

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 12020 ± 320 gas Cox, Evans, et al., 1972
Berkosky, Ellison, et al., 1973
Nicholson and Rademacher, 1974

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 9600 ± 320 gas Cox, Evans, et al., 1972
Berkosky, Ellison, et al., 1973
Nicholson and Rademacher, 1974

Additional references: Jacox, 1994, page 220; Jacox, 2003, page 242

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Evans, et al., 1972
Cox, P.A.; Evans, S.; Orchard, A.F.; Richardson, N.V.; Roberts, P.J., Simple quantitative molecular orbital methods used in connection with photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 26. [all data]

Nicholson and Rademacher, 1974
Nicholson, D.G.; Rademacher, P., Photoelectron spectra and electronic structures of antimony(III) halides, Acta Chem. Scand. Ser. A:, 1974, 28, 1136. [all data]

Berkosky, Ellison, et al., 1973
Berkosky, J.L.; Ellison, F.O.; Lee, T.H.; Rabalais, J.W., Model for calculating spin-orbit interactions with applications to photoelectron spectroscopy, J. Chem. Phys., 1973, 59, 5342. [all data]

Boyle, Jarvis, et al., 1998
Boyle, K.J.; Jarvis, G.K.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.-W., J. Chem. Soc., 1998, Faraday Trans. 94, 2073. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References