Estradiol, 2TMS derivative


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
NIST MS number 332948

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Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySE-30221.2660.Mitra, 1982N2; Column length: 30. m; Column diameter: 0.25 mm
CapillarySE-30231.2671.Mitra, 1982N2; Column length: 30. m; Column diameter: 0.25 mm
CapillarySE-30241.2687.Mitra, 1982N2; Column length: 30. m; Column diameter: 0.25 mm
PackedOV-1225.2660.Voelter, Jung, et al., 1971N2, GasChrom Q

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-52629.Gerhardt, Ludwig-Köhn, et al., 198925. m/0.32 mm/0.25 μm, H2, 2. K/min; Tstart: 120. C; Tend: 270. C
CapillaryDB-52629.Gerhardt, Ludwig-Köhn, et al., 198925. m/0.32 mm/0.25 μm, H2, 2. K/min; Tstart: 120. C; Tend: 270. C
CapillaryDB-52629.Gerhardt, Ludwig-Köhn, et al., 198925. m/0.32 mm/0.25 μm, H2, 2. K/min; Tstart: 120. C; Tend: 270. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryVF-5MS2695.6Tret'yakov, 200730. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101240.2679.Krupcik, Rutten, et al., 1976Column length: 30. m; Column diameter: 0.25 mm
CapillaryOV-101251.2691.Krupcik, Rutten, et al., 1976Column length: 30. m; Column diameter: 0.25 mm

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mitra, 1982
Mitra, G.D., Determination of precise retention indices of steroids using an all-glass solid injection system, J. Chromatogr., 1982, 234, 1, 214-217, https://doi.org/10.1016/S0021-9673(00)81795-1 . [all data]

Voelter, Jung, et al., 1971
Voelter, W.; Jung, G.; Breitmaier, E.; Bouchon, G.; Bayer, E.; Gupta, D., Comparison of the trifluoroacetyl and trimethylsilylether derivaties for gas chromatography of steroids, Anal. Chim. Acta., 1971, 53, 1, 185-188, https://doi.org/10.1016/S0003-2670(01)80085-4 . [all data]

Gerhardt, Ludwig-Köhn, et al., 1989
Gerhardt, K.; Ludwig-Köhn, H.; Henning, H.V.; Remberg, G.; Zeeck, A., Identification of oestrogen metabolites in human urine by capillary gas chromatography and mass spectrometry, Biomed. Environ. Mass Spectrom., 1989, 18, 2, 87-95, https://doi.org/10.1002/bms.1200180202 . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Krupcik, Rutten, et al., 1976
Krupcik, J.; Rutten, G.A.F.M.; Rijks, J.A., The influence of temperature on the separation and characterization of steroids on non-polar glass capillary columns, Chem. zvesti, 1976, 30, 4, 469-479. [all data]


Notes

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