FCH2CO2 anion

• Formula: C₂H₂FO₂^-
• Molecular weight: 77.0350
• IUPAC Standard InChI: InChI=1S/C2H3FO2/c3-1-2(4)5/h1H2,(H,4,5)/p-1 Copy

  
• IUPAC Standard InChIKey: QEWYKACRFQMRMB-UHFFFAOYSA-M Copy
• CAS Registry Number: 513-62-2
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Ion clustering data
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

 +  =

By formula: C₂H₂FO₂^- + H⁺ = C₂H₃FO₂

( • 2) +  = ( • 3)

By formula: (C₂H₂FO₂^- • 2H₂O) + H₂O = (C₂H₂FO₂^- • 3H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

( • ) +  = ( • 2)

By formula: (C₂H₂FO₂^- • H₂O) + H₂O = (C₂H₂FO₂^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

 +  = ( • )

By formula: C₂H₂FO₂^- + H₂O = (C₂H₂FO₂^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

Protonation reactions

 +  =

By formula: C₂H₂FO₂^- + H⁺ = C₂H₃FO₂

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell, Renneboog, et al., 1989
Caldwell, G.; Renneboog, R.; Kebarle, P., Gas Phase Acidities of Aliphatic Carboxylic Acids, Based on Measurements of Proton Transfer Equilibria, Can. J. Chem., 1989, 67, 4, 661, https://doi.org/10.1139/v89-092 . [all data]

Fujio, McIver, et al., 1981
Fujio, M.; McIver, R.T., Jr.; Taft, R.W., Effects on the acidities of phenols from specific substituent-solvent interactions. Inherent substituent parameters from gas phase acidities, J. Am. Chem. Soc., 1981, 103, 4017. [all data]

Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P., Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A), Can. J. Chem., 1978, 56, 1. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Yu, Lina, et al., 2007
Yu, W.B.; Lina, Z.J.; Ding, C.F., Electronic structures and electron detachment energies of halogen substituted acetate anions, XCH2COO- (X=F, Cl, Br), J. Chem. Phys., 2007, 126, 11, 114301, https://doi.org/10.1063/1.2646665 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  EAneutral	Electron affinity of neutral species
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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